Fourier Transform Infra-Red Spectroscopy and Chemical Resistance of Untreated and Alkali Treated Coconut Leaf Sheath Fiber Reinforced Polymer Composites

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In these days, natural fiber and its composites are gaining more interest and utilization of biofibers has increased because of growing concern towards economic, environmental and conservation issues. The present study investigates, Fourier Transform Infra-red (FTIR) spectroscopy and chemical resistance properties on the coconut leaf sheath (CLS) reinforced Phenol Formaldehyde (PF) composites. Naturally woven coconut leaf sheath composites were prepared in both NaOH treated and untreated forms with volume fraction of 60% of sheath and 40% of Phenol Formaldehyde resin. CLS were chemically treated using 5% of NaOH and composite boards were made using a hydraulic hot press at 140°C. FTIR test was conducted for both treated and untreated CLS fiber composites. And it was found that, due to chemical treatment of fibers reduction in lignin and hemicellulose content was observed. The chemical resistance of alkali treated and untreated CLS composites were measured by chemical absorption and chemical thickness swelling methods. Treated and untreated composite samples were then placed in 1N of saline, Hcl, HNO3 and H2SO4 separately. It is also observed that, saline and Hcl have been absorbed more in case of untreated composites and HNO3and H2SO4 is absorbed more in treated composites. These tests were done to know that, these composites can be used in manufacturing products which gives better chemical resistance.

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205-210

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June 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Sudhakar Muniyasamya, Murali M. Reddya, Manjusri Misraa, Amar Mohanty, Biodegradable green composites from bioethanol co-product and poly(butylene adipate-co-terephthalate), Ind. Crops Prod. 43 (2013) 812– 819.

DOI: 10.1016/j.indcrop.2012.08.031

Google Scholar

[2] Farideh Namvar, Mohammad Jawaid, Paridah Md Tahir, Rosfarizan Mohamad, Susan Azizi, Alireza Khodavandi, Heshu Sulaiman Rahman, Majid Dehghan Nayeri, Potential Use of Plant Fibers and their Composites for Biomedical Applications, BioResources. 9 (2014).

DOI: 10.15376/biores.9.3.

Google Scholar

[3] J. Sahari, S.M. Sapuan, E.S. Zainudin, M.A. Maleque, Sugar Palm Tree: A Versatile Plant and Novel Source for Biofibres, biometrics, and Biocomposites, Polym. Renewable Resour. 3 (2012) 61 – 77.

DOI: 10.1177/204124791200300203

Google Scholar

[4] A.K. Mohanty, M. Misra, L.T. Drzal, Sustainable Bio-Composites from Renewable Resources: Opportunities and Challenges in the Green Materials World, J. Polym. Environ. 10 (2002) 19 – 26.

DOI: 10.4324/9781315793245-107

Google Scholar

[5] Wanjun Liu, Manjusri Misra, Per Askeland, Lawrence T. Drzal, Amar K. Mohanty, Green, composites from soy based plastic and pineapple leaf fiber: fabrication and properties evaluation, Polym. 46 (2005) 2710–2721.

DOI: 10.1016/j.polymer.2005.01.027

Google Scholar

[6] Irullappasamy Siva, Jebas Thangiah Winowlin Jappes, Bheemappa Suresha, Investigation on Mechanical and Tribological Behavior of Naturally Woven Coconut Sheath-Reinforced Polymer Composites, Polym. Compos. 33 (2012) 723-732.

DOI: 10.1002/pc.22197

Google Scholar

[7] M. Jannah, M. Mariatti, A. Abu bakar, H.P.S. Abdul Khalil, Effect of Chemical Surface Modifications on the Properties of Woven Banana-Reinforced Unsaturated Polyester Composites, J. Reinf. Plast. Compos. 28 (2009) 1519-1532.

DOI: 10.1177/0731684408090366

Google Scholar

[8] A. Valadez-Gonzalez, J.M. Cervantes-Uc, R. Olayo, P.J. Herrera-Franco, Effect of fiber surface treatment on the fiber–matrix bond strength of natural fiber reinforced composites, Composites Part B. 30 (1999) 309–320.

DOI: 10.1016/s1359-8368(98)00054-7

Google Scholar

[9] A. Varada Rajulu, G. Babu Rao, R. Lakshminarayana Reddy, R. Sanjeevi, Chemical Resistance and Tensile Properties of Epoxy/Polycarbonate Blend Coated Bamboo Fibres, J. Reinf. Plast. Compos. 20 (2001) 335 – 340.

DOI: 10.1177/073168401772678788

Google Scholar

[10] K. John, S. Venkata Naidu. Chemical Resistance of Sisal/Glass Reinforced Unsaturated Polyester Hybrid Composites, J. Reinf. Plast. Compos. 26 (2007) 373 – 376.

DOI: 10.1177/0731684406072524

Google Scholar

[11] A.S. Singha, Vijay Kumar Thakur, Chemical Resistance, Mechanical and Physical Properties of Biofibers-Based Polymer Composites, Polym. -Plast. Technol. Eng. 48 (2009) 736-744.

DOI: 10.1080/03602550902824622

Google Scholar

[12] M. Jawaid, H.P.S. Abdul Khalil, A. Abu Bakar, P. Noorunnisa Khanam, Chemical resistance, void content and tensile properties of oil palm/jute fibre reinforced polymer hybrid composites Mater. Des. 32 (2011) 1014–1019.

DOI: 10.1016/j.matdes.2010.07.033

Google Scholar