Adsorption of Benzene Homologs Materials from Organic Wastewater onto Modified Bentonite

Article Preview

Abstract:

Bentonite has been purified by suspension method and sodiumed with sodium carbonate, and then modified with polyaniline. Finally, characterized by the polarizing microscope, the X-ray diffractometer(XRD) and Fourier infrared spectrometer (FT-IR), in order to determine the optimal preparation technology of polyaniline/bentonite. And the optimal preparation of PAn/MMT is used to research the adsorption dynamics analysis on phenol. The result shows that the sodium ion enters into the bentonite interlayer through ion exchange; When the dosage of bentonite is 5 g, the dosage of FeCl3·6H2O is 2.7 g, the dosage of aniline is 46.5 g, and the dosage of DBSA is 3.26 g, its layer spacing of modified bentonite is 2.823nm, increaseing 1.600nm than the first, so the hydrophobicity and separation effects of the modified bentonite get greatly improvement. And the dosage of PAn/MMT is 0.1 g and the initial concentration of phenol、P-nitrophenol、o-cresol is 10 mg/L, their adsorption rates reach to 51.50%, 80.56%, 62.93%, more high than the sodium bentonite under the same conditinns. It indicates that the modified bentonite is more suitable for the adsorption of benzene homologs.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

662-666

Citation:

Online since:

June 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] L. J. Zhang, P. Hu, J. Wang, R. H. Huang. Adsorption of Amido Black 10B from aqueous solutions onto Zr (IV) surface-immobilized cross-linked chitosan/bentonite composite, Appl. Surf. Sci. 369 (2016) 558–566.

DOI: 10.1016/j.apsusc.2016.01.217

Google Scholar

[2] B. Makhoukhi, M. Djab, M. A. Didi, Adsorption of Telon dyes onto bis-imidazolium modified bentonite in aqueous solutions. J. Envir. Chem. Eng. 3 (2015) 1384–1392.

DOI: 10.1016/j.jece.2014.12.012

Google Scholar

[3] M. Fukushima, R. Okabe, R. Nishimoto, S. Fukuchi, T. Sato, M. Terashima. Adsorption of pentachlorophenol to a humin-like substance–bentonite complex prepared by polycondensation reactions of humic precursors, Appl. Clay Sci. 87 (2014) 136–141.

DOI: 10.1016/j.clay.2013.10.022

Google Scholar

[4] N. Tekin, Y. Ateş, Adsorption of poly(vinylimidazole) from aqueous solutions onto Na-bentonite. Int. J. Min. Proc. 10 (2012) 49–54.

DOI: 10.1016/j.minpro.2012.07.002

Google Scholar

[5] A. Sameeral, B. Fawzi, A. B. A. Leena. Adsorption of phenol using different ty pes of activated bentonites. Separat. ion Purific. Tech. 33 (2003) 1-10.

Google Scholar