Research on Photochromic Compounds with Synthesis and Photochromism of 1-(2-methyl-3-benzofuryl)-2-{2-methyl-5-[4-formyloxyethyl (Rhodamine-B)] phenyl-3-thienyl} Perfluoroyclopentene

Dan Dan Xue; Guan Ming Liao; Chun Hong Zheng; Shou Zhi Pu

doi:10.4028/www.scientific.net/AMR.1003.55

Paper Titles

Research on Photochromic Compounds with Efficient Synthesis and Photochromic Properties of 1-(2-methyl-5-phenyl-3-thienyl)-2-[2-methyl-5-(4-pentylphenyl)-3-thienyl] perfluorocyclopentene
p.39

Research on Photochromic Compounds with Efficient Synthesis and Photochromic Properties of 1-(2-methyl-5-chlorine-3-thienyl)-2-[2-methyl -5-(4-chlorophenyl)-3-thienyl] Perfluorocyclopentene
p.43

Synthesis, Photochromism and Fluorescent Switch of 1-(2-methyl-1-benzofuran-3-yl)-2-(2-methyl-5-(4-benzylamine)-3-thienyl)) perfluorocyclopentene
p.47

Efficient Synthesis, Photochromism and Fluorescence Properties of a Novel Diarylethene Bearing a Fluorene
p.51

Research on Photochromic Compounds with Synthesis and Photochromism of 1-(2-methyl-3-benzofuryl)-2-{2-methyl-5-[4-formyloxyethyl (Rhodamine-B)] phenyl-3-thienyl} Perfluoroyclopentene
p.55

Efficient Synthesis, Photochromism and Fluorescence Properties of a Novel Diarylethene Bearing a Naphthalene
p.59

Synthesis and Properties of 1-[2,5-dimethyl-3-thienyl]-2-[2-methyl-5-(4-pentylphenyl)-3-thienyl] perfluorocyclopentene
p.63

Hydrophobic Modification on Surface of Silicone Rubber by Tetrafluoromethane Radio Frequency Inductively Coupled Plasma
p.69

Study on Corrosion Behavior of Copper-Clad Steel Bars with Unclad Two-End Faces for Grounding Grids in the Coastal Soil
p.74

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1003Research on Photochromic Compounds with Synthesis...

Research on Photochromic Compounds with Synthesis and Photochromism of 1-(2-methyl-3-benzofuryl)-2-{2-methyl-5-[4-formyloxyethyl (Rhodamine-B)] phenyl-3-thienyl} Perfluoroyclopentene

Abstract:

A new photochromic diarylethene compound bearing a rhodamine B unit, 1-(2-methyl-3-benzofuryl)-2-{2-methyl-5-[4-formyloxyethyl (rhodamine-B)] phenyl-3-thienyl} perfluorocyclopentene (1o) was synthesized, and its photochromic properties such as photochromism in solution as well as in a polymethylmethacrylate (PMMA) amorphous film were investigated specfically. 1o exhibits good photochromism upon alternating irradiation with UV light and visible light (> 510 nm) in hexane and a PMMA film. The kinetic experiments showed that the cyclization and cycloreversion processes were zeroth and first order reaction, respectively.

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Periodical:

Advanced Materials Research (Volume 1003)

Pages:

55-58

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1003.55

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Online since:

July 2014

Authors:

Dan Dan Xue, Guan Ming Liao, Chun Hong Zheng*, Shou Zhi Pu

Keywords:

Diarylethene, Photochromic Reaction Kinetics, Photochromism, Rhodamine B

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