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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1004-1005Comparation of Calix[6]arene and its Phosphorus...

Comparation of Calix[6]arene and its Phosphorus Derivative for Complexation of Na⁺, Cu²⁺, Ni²⁺, Pb²⁺, Fe³⁺, Cr³⁺ and ²⁺ UO₂²⁺Ions

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Abstract:

The calix [6] arene and 5,11,17,23,29,35-butyl-25,26,27,28,29,30-diethyl phosphates calix [6] arene (EtPO6) were synthesized and their complexation with different metal ions were investigated. The calix [6] arene and EtPO6 were characterized by IR spectrum. The complexation between the host (calix [6] arene and EtPO6) and the guest (metal ions) were investigated by UV-VIS spectrum and extraction experiments. The results show that the complexation of metal ions by calix [6] aren ranked as Na⁺ > Cu²⁺ > Pb²⁺> UO₂²⁺ > Fe³⁺ > Cr³⁺ > Ni²⁺, and the complexation of metal ions by EtPO6 ranked as UO₂²⁺ > Cu²⁺ > Fe³⁺ > Pb²⁺ > Na⁺ > Cr³⁺ > Ni²⁺. Compared with calix [6] aren, the extraction capacity of UO₂²⁺, Cu²⁺, Fe³⁺, Pb²⁺, Cr³⁺ and Ni²⁺ ions by EtPO6 increased by 37.6%, 10.2%, 10.6%, 9.6%, 2.2%, 4.4%, respectively, while that of Na⁺ ion decreased by 22.3%.

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Advanced Materials and Technologies

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Periodical:

Advanced Materials Research (Volumes 1004-1005)

Pages:

1026-1032

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1004-1005.1026

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Online since:

August 2014

Authors:

Hui Yan Mo, Jing Song Wang*, Heng Yuan Zhang, Qing Wei Guo, Yin An Pi

Keywords:

Calix [6] Arene, Complexation, Extraction, Metal Ions, Phosphorus

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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