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Research on Rheological Behavior of Si3N4-SiC Composites by Gelcasting
Abstract:
Using SiC particles and powder, the modified Si and α-Si3N4 powder as the main raw material, Si3N4-SiC composite materials have been fabricated by gelcasting. The Si3N4-SiC suspension with 75vol% (volume fraction) solid loading exhibits shear thinning rheological behavior under a shear rate from 10 to 160s-1, which meets the requirement of the gelcasting process. The bulk density of the green bodies after solidification is 2.57 g·cm-3 and the flexural strength 16 MPa, the green bodies have a dense and uniform structure. The bulk density and flexural strength of the Si3N4-SiC composites after nitriding are 2.67g·cm-3 and 48 MPa respectively; the strength is higher than that of other industrial products without gelcasting. Well-developed intertwined fibrous Si3N4 crystals grow on the surface of the SiC particles to form a tight microstructure in the Si3N4-SiC composites after firing.
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488-491
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August 2014
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© 2014 Trans Tech Publications Ltd. All Rights Reserved
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