Preparation of Li/MgO Monolithic Catalysts and their Performance for Oxidative Coupling of Methane

Article Preview

Abstract:

A series of Li/MgO/Al2O3/FeCrAl monolithic catalyst with different Li contents were prepared by a wetness impregnation method. The effects of Li contents in the catalysts and reaction conditions such as GHSV and CH4/O2 on the OCM reaction were investigated. The results show that the conversion of CH4 and selectivity of C2 was 38.3% and 27.1%, respectively, which were obtained on the 5%Li/MgO/Al2O3/FeCrAl monolithic catalysts at 850 oC with a GHSV of 24000 mL·g-1·h-1 and CH4/O2 of 2.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1004-1005)

Pages:

648-652

Citation:

Online since:

August 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M.C. Alvarez-Galvan, N. Mota, M. Ojeda, S. Rojas, R.M. Navarro and J.L.G. Fierro. Catal. Today Vol. 171 (2011), p.15.

DOI: 10.1016/j.cattod.2011.02.028

Google Scholar

[2] D. Pan, S.F. Ji, W.H. Wang and C.Y. Li. J. Nat. Gas Chem. Vol. 19 (2010), p.600.

Google Scholar

[3] K. Wang, S.F. Ji, X.J. Shi and J.J. Tang. Catal. Commu. Vol. 10 (2009), p.807.

Google Scholar

[4] U. Simon, S. Arndt, T. Otremba, T. Schlingmann, K.P. Dinse and H. Schubert. Catal. Commu. Vol. 18 (2012), p.132.

Google Scholar

[5] A. Sebastian, L. Guillaume, S.L., H. Raimund, Manfred and M.S. Baerns. Catal. Reviews Vol. 53 (2011), p.424.

Google Scholar

[6] J.Z. Fakhroueian, F. Farzaneh and N. Afrookhteh. Fuel Vol. 87 (2008), p.2512.

Google Scholar

[7] D.J. Driscoll, W. Martir, J.X. Wang and J. Lunsford. Studies in Surface Science and Catal. Vol. 21( 1985), p.403.

Google Scholar

[8] V.R. Choudhary, S. A.R. Mulla, M.Y. Pandit, S.T. Chaudhari and V.H. Rane. J. Chem. Technol. Biotechnol. Vol. 75 (2000), p.828.

Google Scholar

[9] Z. Ulyana, G. Michael, H. Raimund, W. Gisela, F. Wiebke, S. Manfred and S. Robert. ChemCatChem Vol. 3 (2011), p.946.

Google Scholar

[10] H. Liu, J.D. Zhao, C.Y. Li and S.F. Ji. Catal. Today Vol. 105 (2005), p.401.

Google Scholar

[11] I. Yuranow and L. Kiwi-Minsker. Catal. Today Vol. 69 (2001), p.175.

Google Scholar

[12] H. Aritani, H. Yamada, T. Nishio, T. Shiono and S. Imamura. J. Phys. Chem. B Vol. 104 (2000), p.10133.

Google Scholar