Synthesis and Characterization of Eu3+ Doped CaO-Nb2O5-SiO2 Glass-Ceramics

Qiong Song; Hong Bo Zhang; Xiao Wei Zhu; Chun Hui Su

doi:10.4028/www.scientific.net/AMR.1030-1032.185

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1030-1032Synthesis and Characterization of Eu3+ Doped...

Synthesis and Characterization of Eu³⁺ Doped CaO-Nb₂O₅-SiO₂ Glass-Ceramics

Abstract:

The glass-ceramics containing nanocrystalline CaNb₂O₆ phase in the 35%SiO₂-25%Nb₂O₅-20%CaO-15BaO-5%Eu₂O₃(wt%) glass system were prepared by the melt-quench technique followed by a two-stage controlled heat treatment. Samples were characterized by differential thermal analysis, X-ray diffraction, scanning electron microscope, spectrophotometer and fluorescence spectrophotometer. The results shown that glass ceramic phase is CaNb2O6, grain size is about 30 nm, The two-stage controlled heat treatment is beneficial to control of the number and size of grains, thus affecting the transparency of glass ceramic and luminescence properties. The transmittance of the glass ceramics can be up to 80% in the near-infrared light area. The luminescence spectra of Eu³⁺-doped glass and glass–ceramics were recorded at 394 nm excitation wavelength and the luminescence intensity is found to be increased with heat-treatment time due to increase in crystallinity. Fluorescence spectrum showed 4 emission peak, which located in the 578 nm (⁵D₀-⁷F₀), 592 nm (⁵D₀-⁷F₁), 615 nm (⁵D₀-⁷F₂) and 654 nm (⁵D₀-⁷F₃), Eu^{3 +} emission peak intensity in the glass ceramic sample were greater than the substrate glass.

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Periodical:

Advanced Materials Research (Volumes 1030-1032)

Pages:

185-188

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1030-1032.185

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Online since:

September 2014

Authors:

Qiong Song*, Hong Bo Zhang, Xiao Wei Zhu, Chun Hui Su

Keywords:

Eu³⁺ -Doped, Glass Ceramics, Luminescence, Nanocrystallized CaNb₂O₆

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References

[1] WANG Sen, ZHOU Ya-xun, Dai Shi-xun, etal. Journal of Optoelectronics Laser, Vol. 22(2011), pp.1810-1815.

Google Scholar

[2] Upender Gangadharini, Atiar Rahaman Molla, Anal Tarafsder: The American Ceramic Society, 2013, pp.1-8.

Google Scholar

[3] Pornpis Kongputhon, Anuson Niyompan, Rungnapa TIpakontitikul: Journal of Crystal Growth. Vol. 30(2013), pp.116-120.

Google Scholar

[4] CHENG Jin-shu, TIAN Pei-jing, TANG Li-ying: Joural of the Chinese Ceramic Society. Vol. 36(2008), pp.1013-1017.

Google Scholar

[5] Reenamoni Saikia Chalihaa, K. Annapurnaa, Anal Tarafdera: J. Solid State Sciences. Vol. 11(2009), p.1325–1332.

Google Scholar

[6] D. Chen, Y. Yu, P. Huang, H. Lin, Z. Shan, and Y. Wang: Acta Mater. Vol. 58(2010), p.3035–41.

Google Scholar

[7] V. P. Tuyen, T. Hayakawa, M. Nogami, J. R. Duclere, and P. Thomas: J. Solid State Chem. Vol. 183(2010), p.2714.

Google Scholar