Ruthenium-Catalyzed Cascade Ring-Opening Polymerization/Hydroboration for the Synthesis of Low Cross-Linking Poly (6-norbornenyldecaborane) and its Thermal Property

Jun  Peng Li; Han Yang; Yun Liang; Jia Lin Chen; Ming Xie; Lin Min Zhou; Qing Feng Xiong; Wen Lin Li

doi:10.4028/www.scientific.net/AMR.1035.288

Paper Titles

Transformation between Antase and Rutile Titania-Mica Pearlescent Pigment by MnO₂ Induced Process
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Effect of Heat Treatment on Microstructure and Properties of Casting Al-5.5Fe-4Cu-2Zn-0.4Mg-0.5Mn Alloy
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Adsorption of Alcohols onto Zinc Selenide (ZnSe) Crystal Surface
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Development of a New Type of Metal Matrix for Porous Metal Bonded Diamond Grinding Wheels
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Ruthenium-Catalyzed Cascade Ring-Opening Polymerization/Hydroboration for the Synthesis of Low Cross-Linking Poly (6-norbornenyldecaborane) and its Thermal Property
p.288

Property Comparation of Ti-Based and Cr-Based PVD Nitride Coatings
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The Preparation of Calcium Carbonate Modified High Water-Absorbing Resin
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Effect of Y on Microstructure and Mechanical Properties of Mg-6Al-1Zn-1.8Gd Magnesium Alloy
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Resin Material Used in Methyl Acrylate Hydrolysis Reaction
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1035Ruthenium-Catalyzed Cascade Ring-Opening...

Ruthenium-Catalyzed Cascade Ring-Opening Polymerization/Hydroboration for the Synthesis of Low Cross-Linking Poly (6-norbornenyldecaborane) and its Thermal Property

Abstract:

The ruthenium catalyzed hydroboration of decaborane for the synthesis of low cross-linking poly (organodecaborane) is reported for the first time in one-pot. Based on the ruthenium-catalyzed cascade ring-opening polymerization/hydroboration reaction, the poly (6-norbornenyldecaborane) was obtained with well-defined structure, the final char yield is up to 81%. This method offers a complementary approach for the synthesis of decaborane-containing polymers.

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Proceedings of 2014 International Conference on Material Science and Engineering

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Periodical:

Advanced Materials Research (Volume 1035)

Pages:

288-291

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1035.288

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Online since:

October 2014

Authors:

Jun Peng Li*, Han Yang, Yun Liang, Jia Lin Chen, Ming Xie, Lin Min Zhou, Qing Feng Xiong, Wen Lin Li

Keywords:

Char Yield, Hydroboration, One-Pot, Ruthenium-Catalyzed, Thermal Resistance

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