Performance of an Maleic Anhydride Based Polymers as Scale Inhibitor and Iron (III) Scaling in Industrial Cooling Water Systems

Article Preview

Abstract:

The precipitation of Ca3(PO4)2 scale on pipe surfaces widely occurs in numerous industrial processes. For the control of Ca3(PO4)2 scales, a novel environmentally friendly type of scale inhibitor Maleic anhydride (MA) - allypolyethoxy carboxylate (APEM) was synthesized. Structures of APEG, APEM, and MA-APEM were identified by FT-IR. MA-APEM possess excellent Ca3(PO4)2 inhibition, approximately 96.7 % at threshold dosage of 6 mg/L, and it also have superior ability to iron (III) dispersion in solutions approximately 24.3 % in the presence of MA-APEM when the dosage exceeds 6 mg/L. Inhibitor of MA-APEM can be used safely in cooling water systems.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1044-1045)

Pages:

79-82

Citation:

Online since:

October 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] X.X. Gu, F.X. Qiu, X. Zhou, J. Qi, Y. Zhou, D. Yang, Q. Guo, X.R. Guo, Preparation and application of polymers as inhibitors for calcium carbonate and calcium phosphate scales, Int. J. Polym. Mater. Polym. Biomater. 62 (2013) 323-329.

DOI: 10.1080/00914037.2012.670824

Google Scholar

[2] C.E. Fu, Y.M. Zhou, G.Q. Liu, J.Y. Huang, W.D. Wu, W. Sun, Carboxylate-ended poly(ethylene glycol) macromonomers and their copolymers as inhibitors for calcium phosphate and calcium sulfate, Int. J. Polym. Mater. 61 (2012) 341-356.

DOI: 10.1080/00914037.2011.584230

Google Scholar

[3] Atamanenko, I.A. Kryvoruchko, L. Yurlova, E. Tsapiuk Study of the CaSO4 deposits in the presence of scale inhibitors, Desalination 147 (1-3) (2002) 257-262.

DOI: 10.1016/s0011-9164(02)00547-7

Google Scholar

[4] M. A-H. Luai, Q. Abdul, A. A-O. Dhawi, Calcium sulfate scale deposition on carbon steel and titanium, Desalin. Water Treat. 51 (2013) 2521-2528.

Google Scholar

[5] Z. Kiaei, A. Haghtalab, Experimental study of using Ca-DTPMP nanoparticles in inhibition of CaCO3 scaling in a bulk water process, Desalination 338 (2014) 84-92.

DOI: 10.1016/j.desal.2014.01.027

Google Scholar

[6] P. Kjellin, X-ray diffraction and scanning electron microscopy studies of calcium carbonate electrodeposited on a steel surface, Colloids and Surfaces A: Physicochem Eng. Aspects. 212 (2003) 19 -26.

DOI: 10.1016/s0927-7757(02)00296-0

Google Scholar

[7] Suharso, Buhani, B. Syaiful, E. Teguh, Gambier extracts as an inhibitor of calcium carbonate (CaCO3) scale formation, Desalination 265 (2011) 102-106.

DOI: 10.1016/j.desal.2010.07.038

Google Scholar

[8] F. Liu, X.H. Lu, W. Yang, J.J. Lu, H.Y. Zhong, X. Chang, C.C. Zhao, Optimizations of inhibitors compounding and applied conditions in simulated circulating cooling water system, Desalination 313 (2013) 18-27.

DOI: 10.1016/j.desal.2012.11.028

Google Scholar

[9] K. Du, Y.M. Zhou, L.Q. Wang, Y.Y. Wang, Fluorescenr-tagged no phosphate and nitrogen free calcium phosphate scale inhibitor for cooling water systems, J. Appl. Polym. Sci. 113 (2009) 1966-(1974).

DOI: 10.1002/app.30213

Google Scholar

[10] G.Q. Liu, Y.M. Zhou, J.Y. Huang, Q.Z. Yao, L. Ling, P.X. Zhang, X.F. Zhong, C.E. Fu, W.D. Wu, W. Sun, Z.J. Hu, Carboxylate-terminated double-hydrophilic block copolymer as an effective and environmentally friendly inhibitor for carbonate and sulfate scales in cooling water systems, Water Air Soil Poll. 223 (2012).

DOI: 10.1007/s11270-012-1133-5

Google Scholar

[11] L. Ling, Y.M. Zhou, J.Y. Huang, Q.Z. Yao, G.Q. Liu, P.X. Zhang, W. Sun, W.D. Wu, Carboxylate-terminated double-hydrophilic block copolymer as an effective and environmental inhibitor in cooling water systems, Desalination 304 (2012) 33-40.

DOI: 10.1016/j.desal.2012.07.014

Google Scholar

[12] A.A. Koelmans, H.A. Vander, L.M. Knijff, R.H. Aalderink, Integrated modeling of eutrophication and organic contaminant fate & effects in aquatic ecosystems, Water Res. 35(15) (2001) 3517-3536.

DOI: 10.1016/s0043-1354(01)00095-1

Google Scholar