The Effect of the Calcium Leaching on the Microstructure and Rupture Strength of CA Mortar

Article Preview

Abstract:

This paper deals with the effect of calcium leaching on the microstructure and rupture strength of cement asphalt (CA) mortar. It is conducted by an accelerated experiment method with species obtained from construction site. Results show that the leaching process mainly contains a total leaching of CaOH2 (CH) and some other cement hydrations. The leaching is proved by the “portlandite dissolution front” on the cross-section of species using a reagent of phenolphthalein. As time goes, the species are continually leached, and then the loss of mass and porosity ratio are obviously increased. Fick’s law can describe the relationship between leaching depth and time very well. The loss of mass and increasing of porosity ratio respond to the shrinking of mechanical properties of CA mortar.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1049-1050)

Pages:

325-334

Citation:

Online since:

October 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] K. Yokozeki, K. Watanabe, N. Sakata, N. Otsuki. Modeling of leaching from cementitious materials used in underground environment. Applied Clay Science. 26 (2004) 293-308.

DOI: 10.1016/j.clay.2003.12.027

Google Scholar

[2] Christophe Carde, Raoul Francois, Jean-Michel Torrenti. Leaching of both calciumhydroxide and C-S-H from cement paste . Cement and Concrete Research. 26 (1996) 1257-1268.

DOI: 10.1016/0008-8846(96)00095-6

Google Scholar

[3] U. Schneider, S. -W. Chen. Deterioration of high-performance concrete subjected to attack by the combination of ammonium nitrate solution and flexure stress. Cement and Concrete Researc. 35 (2005) 1705-1713.

DOI: 10.1016/j.cemconres.2004.11.011

Google Scholar

[4] Franz H, Heukamp. Chemomechanics of Calcium Leaching of Cement-Based Materials at Different Scales. Massachusetts Institute of Technology. Februray (2003).

Google Scholar

[5] Detlef Kuhl, Falko Bangert, Gunther Meschke. Coupled chemo-mechanical deterioration of cementitious materials Part I. International Joural of Solids and Structure. 41 (2004) 15-40.

DOI: 10.1016/j.ijsolstr.2003.08.005

Google Scholar

[6] Christophe Carde, Raoul Francois. Modelling the loss of strengthand porosity increase due to the leaching of cement pastes. Cement & Concrete Composites. 21 (1999) 181-188.

DOI: 10.1016/s0958-9465(98)00046-8

Google Scholar

[7] Detlef Kuhl, Falko Bangert, Gunther Meschke. Coupled chemo-mechanical deterioration of cementitious materials Part II. International Journal of Solids and Structures. 41 (2004) 41-67.

DOI: 10.1016/j.ijsolstr.2003.08.004

Google Scholar

[8] L.L. Wong, H. Asrah, M.E. Rahman, M.A. Mannan. Effects of Aggressive Ammonium Nitrate on Durability Properties of Concrete. International Journal of Civil, Architectural Science and Engineering. Vol: 7 No: 1, (2013).

Google Scholar

[9] V.H. Nguyen, B. Nedjar, J.M. Torrenti. Chemo-mechanical coupling behaviour of leached concrete Part II. Nuclear Engineering and Design. 237 (2007) 2090-(2097).

DOI: 10.1016/j.nucengdes.2007.02.012

Google Scholar

[10] Christophe Carde, Raoul Francois. Effect of the leaching of calciumhydroxide from cement paste on mechanical and physical properties. Cement and Concrete Research. Vol. 27, No. 4, pp.539-550, (1997).

DOI: 10.1016/s0008-8846(97)00042-2

Google Scholar

[11] Kazuko Haga, Shunkichi Sutou, Michihiko Hironaga, Satoru Tanaka, Shinya Nagasaki. Effects of porosity on leachingof Ca from hardened ordinary Portland cement paste. Cement and Concrete Research. 35 (2005) 1764-1775.

DOI: 10.1016/j.cemconres.2004.06.034

Google Scholar

[12] P. Faucon, P. Le Bescop, F. Adenot, P. Bonville, J.F. Jacquinot. Leaching of cement-Study of the surface layer. Cement and Concrete Research. Vol. 26, No. 11, pp.1707-1715, (1996).

DOI: 10.1016/s0008-8846(96)00157-3

Google Scholar

[13] F. Bernard, S. Kamali-Bernard, W. Prince. 3D multi-scale modelling of mechanical behaviour of sound and leached mortar. Cement and Concrete Research. 38 (2008) 449-458.

DOI: 10.1016/j.cemconres.2007.11.015

Google Scholar

[14] J.M. Torrenti, T. de Larrard, F. benboudjema. Coupling between leaching and creep of concrete.

Google Scholar

[15] G. Constantinides, F.J. Ulm. Multi-scale poro-elastic properties of cement-based materials. Massachusetts Institute of Technology.

Google Scholar

[16] E. Stora, B. Bary, Q. -C. He, E. Deville, P. Montarnal. Modeling and simulations of the chemo–mechanical behavior of leached cement-based materials. Cement and Concrete Research. 39 (2009) 763-772.

DOI: 10.1016/j.cemconres.2009.05.010

Google Scholar

[17] Marc Mainguy, Claire Tognazzi, Jean-Michel Torrenti. Modelling of leaching in purecement paste and mortar. Cement and Concrete Research. 30 (2000) 83-90.

DOI: 10.1016/s0008-8846(99)00208-2

Google Scholar

[18] Dariusz Gawin, Francesco Pesavento, Bernhard A. Schrefler. Modeling deterioration of cementitious materials exposed to calcium leaching in non-isothermal conditions. Comput. Methods Appl. Engrg. 198 (2009) 3051-3083.

DOI: 10.1016/j.cma.2009.05.005

Google Scholar

[19] A. Sellier, L. Buffo-Lacarriere, M. EI Gonnouni, X. Bourbon. Behavior of HPC nuclear waste disposal structures in leaching environment. Nuclear Engineering and Design. 241 (2011) 402-414.

DOI: 10.1016/j.nucengdes.2010.11.002

Google Scholar

[20] Irene Man-Chi Lo, Chong-I. Tang, Xiangdong Li, Chisun Poon. Leaching and Microstructural Analysis of Cement-Based Solidified Wastes. Environ. Sci. Technol. 2000, 34, 5038-5042.

DOI: 10.1021/es991224o

Google Scholar

[21] T. Rougelot, N. Burlion, D. Bernard, F. Skoczylas. Cracking due to leaching in cementitious composites.

Google Scholar

[22] S. Goni, M.S. Hernadez, A. Guerrero, M.P. Lorenzo. Effect of temperature on the leaching performance of a simulated cement-based immobilization system. Construction and Building Materials. Vol. 10, No. 3, pp.171-177, (1996).

DOI: 10.1016/0950-0618(95)00082-8

Google Scholar

[23] Franz-Josef Ulm, Eric Lemarchand, Franz H. Heukamp. Elements of chemomechanics of calcium leaching of cement-based materials at different scales. Engineering Fracture Mechanics. 70 (2003) 871-889.

DOI: 10.1016/s0013-7944(02)00155-8

Google Scholar

[24] Bei Huang, Chunxiang Qian. Experiment study of chemo-mechanical coupling behavior of leached concrete. Construction and Building Materials. 25 (2011) 2649-2654.

DOI: 10.1016/j.conbuildmat.2010.12.014

Google Scholar

[25] Gilles Escadeillas. Ammonium Nitrate Attack on Cementitious Materials.

Google Scholar

[26] W.J. Mccarter, G. Starrs, T.M. Chrisp. Diffusion kinetics in cementitious binders. Journal of Materials Science Letters. 19, 2000, 1279-1280.

DOI: 10.1023/a:1006758410216

Google Scholar

[27] Dongmei Tian, Qiang Yuan, Rong Zhu. Effect of Water on Static Mechanical Properties of Cement Emulsified Asphalt Mortar. Journal of the Chinese Ceramic Society. Vol. 40, No. 11, 2012, 1544-1552.

Google Scholar

[28] O. Coussy, F. -J. Ulm. Creep and plasticity due to chemomechanical couplings. Archive of Applied Mechanics. 66 (1996) 523-535.

DOI: 10.1007/bf00808142

Google Scholar

[29] J.M. Torrenti, V.H. Nguyen, H. Colina, F. Le Maou, F. Benboudjema, F. Deleruyelle. Coupling Between Leaching and Mechanical Behaviour of Concrete. Cement and Concrete Research 38 (2008) 816-821.

DOI: 10.1016/j.cemconres.2008.01.012

Google Scholar

[30] Nicolas Burlion, Dominique Bernard, Da Chen. Microstructure analysis of a cementitious material during leaching process. Cement and Concrete Research. 36 (2006) 346-357.

DOI: 10.1016/j.cemconres.2005.04.008

Google Scholar

[31] Christophe Carde, Raoul Francois. Modelling the loss of strength and porosity increase due to the leaching of cement pastes. Cement and Concrete Composities. 21 (1999) 181-188.

DOI: 10.1016/s0958-9465(98)00046-8

Google Scholar