The Thermodynamic Characterization in Cs-I-O Reaction

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Abstract:

Base on the thermodynamic calculation, CsI (s) does not decompose to Cs (s) and I (s) at 600°C, either does not from I2(g), CsO(g), CsO2(g), Cs2O(g), and Cs2O3(g). However during the experiment when CsI(s) is heated above to 200 °C at 1 atm the purple vapor can clearly be obviated. The vapor should be I2(g). It is because the incomplete boing of I- which in the CsI compound is evaporation. In this paper, we are interesting in CsI properties during heating and calculation the Cs-I-O thermodynamic characterizations by the thermodynamic data books.

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162-165

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October 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Marco Stampanoni, Gunther Borchert, Peter Wyss, Rafael Abela, Bruce Patterson, Steven Hunt, Detlef Vermeulen, .. Peter Rüegsegger, High resolution X-ray detector for synchrotron-based microtomography, Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 491(1-2), (2002).

DOI: 10.1016/s0168-9002(02)01167-1

Google Scholar

[2] A. Ananenko, A. Fedorov, A. Lebedinsky, P. Mateychenko, V. Tarasov, Yu. Vidaj, structural dependence of CsI(Tl) film scintillation properties, Semiconductor Physics, Quantum Electronics & Optoelectronics, 7(3), (2004) 297-300.

DOI: 10.15407/spqeo7.03.297

Google Scholar

[3] W.D. Callister, Materials Science and Engineering, 3th version, Mc Graw Hill, USA (1994) 28.

Google Scholar

[4] http: /en. wikipedia. org/wiki/Solubility_table#C.

Google Scholar

[5] Barin I (1989), Thermochemical Data of Pure Substances. VCH verrlagsgesellschaft mbh, New York, USA, pp.446-448.

Google Scholar

[6] MW Chase, Jr. CA Davies, JR Downey, Jr. DJ Furip, RA McDonald, and AN Syverud (1985) JANAF Thermochemical Tables Third Edition. American Chemical Society, New York, USA, p. pp.959-960.

Google Scholar