Experimental Study on Photocatalytic Mercury Removal by Titanium Dioxide

Article Preview

Abstract:

TiO2 hollow sphere was synthesized by hydrothermal method using Trifluoroacetic acid (TFA) and Ti (SO4)2 as raw materials. The photocatalytic properties of TiO2 hollow sphere were evaluated by the photocatalytic oxidization of elemental mercury (Hg0) in simulated flue gas. The as-prepared samples were well characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-visible diffuse reflectance spectroscopy and nitrogen sorption/desorption. The results show that only anatase phase for TiO2 the hollow sphere is obtained. The average diameter is about 800nm and the shell thickness was about 200nm. The sample prepared with TFA has better photocatalytic properties than P25.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1073-1076)

Pages:

743-746

Citation:

Online since:

December 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] T.D. Brown, D.N. Smith, R.A. Hargis, W.J. O'Dowd, Mercury measurement and its control: What we know, have learned, and need to further investigate, J. Air Waste Manage. Assoc. 49 (1999) 628–640.

DOI: 10.1080/10473289.1999.10463844

Google Scholar

[2] Emission standard of air pollutants for power plants. GB 13223-(2011).

Google Scholar

[3] Seok Ho Jeon, Yujin Eom, Tai Gyu Lee, Photocatalytic oxidation of gas-phase elemental mercury by nanotitanosilicate fibers, Chemosphere, 71(2008)969–974.

DOI: 10.1016/j.chemosphere.2007.11.050

Google Scholar

[4] Hoffmann M R, Martin S T,Choi W.Environmental applications of semiconductor photocatalysis.Chemical Reviews, 1995, 95(1): 69-96.

Google Scholar

[5] Jiaguo Yu, Lei Shi, One-pot hydrothermal synthesis and enhanced photocatalytic activity of trifluoroacetic acid modified TiO2 hollow microspheres, Journal of Molecular Catalysis A: Chemical 326 (2010) 8–14.

DOI: 10.1016/j.molcata.2010.04.016

Google Scholar

[6] Jiaguo Yu, Wenguang Wang, Bei Cheng, and Bao-Lian Su. Enhancement of photocatalytic activity of mesporous TiO2 powders by hydrothermal surface fluorination treatment. Journal of Physical Chemistry C, 2009, 113, 6743-6750.

DOI: 10.1021/jp900136q

Google Scholar