Study on Different Synthesis Methods of Spherical YAG:Ce3+ Phosphor and its Luminescence Properties

Article Preview

Abstract:

Spherical YAG:Ce3+ phosphors were synthesized by three different routes namely sol-gel method, co-precipitation method and solvethermal method. The microstructure, crystallization and luminescent properties of the phosphors were studied in order to find the best processing parameter for spherical shape and good luminescence properties of YAG:Ce3+ phosphor. Adding citric acid to the precursor solution resulted in the formation of spherical particles in sol-gel method. YAG:Ce3+ phosphor made by co-precipitation method was separated with PEG2000, and its spherical particles of size was around 500nm. The hydro-thermal method could get perfect spherical appearance, but it needed heat treatment improve the luminescence property.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

371-376

Citation:

Online since:

February 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Blasse G, Bril A. A new phosphor for flying-spot cathode-ray tubes for color television: yellow emitting Y3Al5O12: Ce3+. Appl Phys Lett, 1967, 11: 53–5.

DOI: 10.1063/1.1755025

Google Scholar

[2] Y. Pan, M. Wu, Q. Su, Tailored photoluminescence of YAG: Ce phosphor through various methods, J. Phys. Chem. Solids, 2004, 65: 845–850.

DOI: 10.1016/j.jpcs.2003.08.018

Google Scholar

[3] Kasuya R, Kawano A, Isobe T, Kuma H, Katano J. Characteristic optical properties of transparent color conversion film prepared from YAG: Ce3+ nanoparticles. Appl Phys Lett, 2007, 91: 111916.

DOI: 10.1063/1.2785131

Google Scholar

[4] Yang H, Lee DK, Kim YS. Spectral variations of nano-sized Y3Al5O12: Ce phosphors via co-doping/substitution and their white LED characteristics. Mater Chem Phys, 2009, 114: 665–669.

DOI: 10.1016/j.matchemphys.2008.10.019

Google Scholar

[5] Jong-Uk Kim, Yong-Seog Kim, Heesun Yang, Nanocrystalline Y3Al5O12: Ce phosphor-based white light-emitting diodes embedded with CdS: Mn/ZnS core/shell quantum dots, Materials Letters, 2009, 63: 614-616.

DOI: 10.1016/j.matlet.2008.12.001

Google Scholar

[6] Haiying SUN, Xiyan ZHANG, Zhaohui BAI , Synthesis and characterization of nano-sized YAG: Ce, Sm spherical phosphors, Journal of Rare Earths, 2013, 31(3): 231-234.

DOI: 10.1016/s1002-0721(12)60263-4

Google Scholar

[7] Y. Pan, M. Wu, Q. Su, Comparative investigation on synthesis and photoluminescence of YAG: Ce phosphor, Mater. Sci. Eng.: B 2004, 106: 251–256.

Google Scholar

[8] Takashi Ogi, Asep Bayu Dani Nandiyanto, Wei-Ning Wang, et al. Direct synthesis of spherical YAG: Ce phosphor from precursor solution containing polymer and urea, Chemical Engineering Journal, 2012, 210: 461–466.

DOI: 10.1016/j.cej.2012.09.033

Google Scholar

[9] C.W. Won, H.H. Nersisyan, H.I. Won, et al. Efficient solid-state route for the preparation of spherical YAG: Ce phosphor particles, Journal of Alloys and Compounds, 2011, 509: 2621–2626.

DOI: 10.1016/j.jallcom.2010.11.143

Google Scholar

[10] Y.C. Kang, I.W. Lenggoro, S.B. Park, K. Okuyama, YAG: Ce phosphor particles prepared by ultrasonic spray pyrolysis, Mater. Res. Bull. 2000, 35: 789–798.

DOI: 10.1016/s0025-5408(00)00257-9

Google Scholar

[11] S.H. Lee, H.Y. Koo, S.M. Lee, Y.C. Kang, Characteristics of Y3Al5O12: Ce phosphor powders prepared by spray pyrolysis from ethylenediaminetetraacetic acid solution, Ceram. Int. 2010, 36: 611–615.

DOI: 10.1016/j.ceramint.2009.09.041

Google Scholar

[12] Hsuan-Min Lee, Chao-Chi Cheng, Chi-Yuen Huang, The synthesis and optical property of solid-state-prepared YAG: Ce phosphor by a spray-drying method, Materials Research Bulletin, 2009, 44(5, 6): 1081-1085.

DOI: 10.1016/j.materresbull.2008.10.006

Google Scholar

[13] Tao Han, Shixiu Cao, Dachuan Zhu, Cong Zhao, Mingxing Ma, Mingjing Tu, Jin Zhang, Effects of annealing temperature on YAG: Ce synthesized by spray-drying method, Optik - International Journal for Light and Electron Optics, 2013, 124(18): 3539-3541.

DOI: 10.1016/j.ijleo.2012.10.067

Google Scholar

[14] Saladino M.L., Nasillo G., Martino D.C., and Caponetti E., Synthesis of Nd: YAG nanopowder using the citrate method with microwave irradiation, J. Alloys. Compd., 2010, 491(1–2): 737.

DOI: 10.1016/j.jallcom.2009.11.054

Google Scholar

[15] Ankam Bhaskar, Horng-Yi Chang, Tsun-Hsu Chang, et al. Microwave annealing of YAG: Ce nanophosphors, Materials Letters, 2012, 78: 124-126.

DOI: 10.1016/j.matlet.2012.03.038

Google Scholar

[16] Yanhui Li, Jihua Zhang, Qingquan Xiao, et al. Synthesis of ultrafine spherical YAG: Eu3+ phosphors by MOCVD, Material Letters, 2008, 62: 3787-3789.

DOI: 10.1016/j.matlet.2008.03.061

Google Scholar

[17] Y. Kang, I. Lenggoro, S. Park, K. Okuyama, Photoluminescence characteristics of YAG: Tb phosphor particles with spherical morphology and non-aggregation, J. Phys. Chem. Solids, 1999, 60: 1855–1858.

DOI: 10.1016/s0022-3697(99)00191-2

Google Scholar