Synthesis and Characterization of Copolymer of Dimethyldiallylammonium Chloride and Acrylamide

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The inverse emulsion polymerization of dimethyldiallylammonium chloride (DMDAAC) with acrylamide (AM) was carried out using a redox system as initiator, petroleum ether as oil, and Span-85 and Tween-80 as emulsifiers. The cationic degree of the copolymer increased markedly when AM was fed into the system in batch. The effect of DMDAAC content on the intrinsic viscosity ([η]) and solubility of the copolymer, and the methods of feeding AM on the cationic degree and solubility of the copolymer was studied in this work. The cationic degree of 39.8% of the copolymer was achieved. When the molar ratio of AM to DMDAAC was 4.0, the copolymer with [η] of 10.02 dl/g and the dissolving time less than 15min was obtained. The structure of the copolymer was also characterized by IR spectrum.

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Periodical:

Advanced Materials Research (Volumes 11-12)

Main Theme:

Edited by:

Masayuki Nogami, Riguang Jin, Toshihiro Kasuga and Wantai Yang

Pages:

753-756

DOI:

10.4028/www.scientific.net/AMR.11-12.753

Citation:

F. M. Wu and X. Y. Zhang, "Synthesis and Characterization of Copolymer of Dimethyldiallylammonium Chloride and Acrylamide", Advanced Materials Research, Vols. 11-12, pp. 753-756, 2006

Online since:

February 2006

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$35.00

[1] W. Baade, D. Hunkeler and A.E. Hamielec: J. Appl. Polym. Sci. Vol. 38 (1989), p.185.

[2] Y.Q. Lin, H. Pledger Jr. and G.B. Butler: J. Macro. Sci. Chem. A. Vol. 25 (1988), p.999.

[3] Y.Q. Lin and G.B. Butler: J. Macro. Sci. Chem. A. Vol. 26 (1989), p.681.

[4] H.Z. Zhao, Q.Y. Yue, B.Y. Gao, H. Yu and Z.K. Luan: Fine Chem. Vol. 11 (2001), p.645.

[5] S.J. Hou and R.H. Ha: Acta Polym. Sin. Vol. 3 (1995), p.349.

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