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A New Organic-Inorganic Hybrid Based on L-Arginine and Polyoxoanion

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Abstract:

Modifying polyoxometalates with organic and/or metal-organic moieties is a widely adopted method for broading the range of properties. In this work a new polyoxometalate constructed from Anderson-type polyoxoanions and L-arginine (Arg = L-arginine) molecules Na [CrMo6(OH)6O18]}(H2Arg)2·8H2O(1) has been synthesized via conventional method and characterized by routine techniques. Single-crystal X-Ray diffraction analysis shows that compound 1 is constructed by chiral L-arginine grafted Anderson-type clusters, sodium cation and water molecules which are further stabilized by hydrogen bonding interactions constitute 3D supramolecular networks. In addition, both antitumor behavior and photocatalytic activities of compound 1 were investigated.

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Advanced Materials Research V View Preview

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Periodical:

Advanced Materials Research (Volume 1105)

Pages:

335-338

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1105.335

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Online since:

May 2015

Authors:

Qiong Wu, Jing Lu, Xiao Lin Ji, Tao Yu Zou, Zhen Fang Qiao, Hong Ping Ju, Hai Wang*

Keywords:

Amino-Acid, Chiral, Polyoxometalates, Property Research

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] P.J. Hagrman, D. Hagrman , J. Zubieta , Angew. Chem., Int. Ed., Vol. 38, (1999) 2638.

DOI: 10.1002/(sici)1521-3773(19990917)38:18<2638::aid-anie2638>3.0.co;2-4

Google Scholar

[2] D.A. Loy , KJ Shea. Chem. Rev. Vol. 95, 1431(1995).

Google Scholar

[3] A.P. Wight , M. E. Davis. Chem. Rev., Vol. 102, 3589 (2002).

Google Scholar

[4] C.R. Kagan, D.B. Mitzi , C.D. Dimitrakopoulos . Science., Vol. 286, 945 (1999).

Google Scholar

[5] X.L. Wang, C. Qin, E.B. Wang, Z.M. Su, Y.G. Li , L. Xu. Angew. Chem., Int. Ed., Vol. 45, (2006)7411.

Google Scholar

[6] K. Wassermann, M.H. Dickman , M.T. Pope. Angew. Chem. Int. Ed., Vol. 36, (1997)1445.

Google Scholar

[7] T. Liu, Y.J. Zhang, Z.M. Wang , S. Gao. J. Am. Chem. Soc., Vol. 130, (2008)10500.

Google Scholar

[8] A. Müller, S.Q.N. Shah, H. Bögge , M. Schmidtmann. Nature., Vol. 397, (1999). 48.

Google Scholar

[9] Q. Wu, Y.G. Li, Y.H. Wang, E.B. Wang , R. Clérac. Inorg. Chem., Vol. 48, (2009)1606.

Google Scholar

[10] J.M. Breen , W. Schmitt. Angew. Chem., Int. Ed., Vol. 47, (2008)6904.

Google Scholar

[11] A. Müller, V. P. Fedin, C. Kuhlmann, H. D. Fenske, G. Baum, H. Bögge , B. Hauptfleisch. Chem. Commun., (1999)1189.

Google Scholar

[12] S.T. Zheng, J. Zhang, X.X. Li, W.H. Fang , G.Y. Yang, J. Am. Chem. Soc., Vol. 132, (2010)15102.

Google Scholar

[13] A Stein, BJ Melde , RC Schroden. Adv. Mater., Vol. 12, (2000)1403.

Google Scholar

[14] B.J. Miflin , P. J. Lea. Annual Review of Plant Physiology., Vol. 28, (1977)299.

Google Scholar

[15] H.N. Christensen. Physiol. Rev., Vol. 70, (1990)43.

Google Scholar

[16] S. Henikoff , J. G. Henikoff. Proceedings of the National Academy of Sciences of the United States of America., Vol. 89, (1992)10915.

Google Scholar

[17] B.L. Vallee , D.S. Auld. J. Biochem., Vol. 29, (1990) 5647.

Google Scholar

[18] BA Diner , Biochimica. Biophysica Acta (BBA)-Bioenergetics., Vol. 1503, (2001)147.

Google Scholar

[19] L. Shi-wei, W. Qiong and W. En-bo CHEMICAL RESEARCH IN CHINESE UNIVERSITES Vol 28 (2012), P. 375-378.

Google Scholar

[20] R. Wang, H. Liu, M.D. Carducci, T Jin, C. Zheng , Z. Zheng. Inorg. Chem., 40, (2001)2743.

Google Scholar