The Effect of KOH Activation in Synthesis and Characterization of Zeolitic Imidazolate Frameworks-8 (ZIF-8) Templated Mesoporous Carbon

Miratul Alifah; Vika Ayu Devianti; Amirul Mukminin; Yulia Rachmawati; Muhammad Ainul Fahmi; Ratna Ediati

doi:10.4028/www.scientific.net/AMR.1123.78

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1123The Effect of KOH Activation in Synthesis and...

The Effect of KOH Activation in Synthesis and Characterization of Zeolitic Imidazolate Frameworks-8 (ZIF-8) Templated Mesoporous Carbon

Abstract:

ZIF - 8 material has been successfully synthesized through a reaction between zinc nitrate hexahydrate with 2 - metilimidazol in the dimethylformamide solvent in solvotermal condition. Synthesis process is carried out at 120oC for 24 hours . The results show that the characterization by XRD diffractogram synthesized ZIF - 8 has a characteristic peak at 2θ = 7.4^o; 12.7^o; 16.5^o and 18.0^o corresponding to the characteristic peaks of ZIF - 8 standard . The results of ZIF - 8 templated carbon show the XRD pattern of amorphous carbon material, while the carbon activated KOH show peak K₂CO₃ at 2θ = 31.6o. FTIR spectra of synthesized ZIF - 8 has a absorption peak at 420; 760 ; 990 ; 1147 and 1585 cm^-1 which is the characteristic absorption peak of ZIF-8 solids. Then ZIF - 8 characteristic peaks disappear after activated with KOH. Morphology of the ZIF-8 has plumage regular rectangular in shape , and morphology of the resulting carbon particles are also the same rectangular shape with ZIF-8 template.

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Periodical:

Advanced Materials Research (Volume 1123)

Pages:

78-83

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1123.78

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Online since:

August 2015

Authors:

Miratul Alifah, Vika Ayu Devianti, Amirul Mukminin, Yulia Rachmawati, Muhammad Ainul Fahmi, Ratna Ediati*

Keywords:

Furfuryl Alcohol, KOH Activation, Nanoporous Carbon, Template, ZIF-8

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