Investigation of Gamma Radiation on Hydroxyapatite Synthesized from Chicken Eggshell by ESR Spectroscopy

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The purpose of this work was investigated the properties and characteristic of gamma radiation on hydroxyapatite which synthesized from biowaste chicken eggshell via the chemical precipitation method. The hydroxyapatite from biowaste chicken eggshell was gamma irradiated in rage 10 Gy to 1 kGy and analyzed by electron spin resonance (ESR). The optimize parameter set ESR read out of Hydroxyapatite were such as microwave power and modulate amplitude corresponded 63.34 mW and 2 mT, respectively. The ESR signal based on the measurement of the concentration of radiation induced radicals CO2- molecular ion also formed in hydroxyapatite. The relative of ESR intensity and dose response was linear. These experiments indicated that the hydroxyapatite from biowaste chicken eggshell could be used good dosimeter in rage 20 to 100 Gy.

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416-420

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October 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Rokhmistrov, D.V., Nikolov, O.T., Gorobchenko, O.A. and Loza, K.I., 2012, Study of Structure of Calcium Phosphate Materials by Means of Eletron Spin Resonance, Appl. Radiat. Isotopes, Vol. 70, pp.2621-2626.

DOI: 10.1016/j.apradiso.2012.07.020

Google Scholar

[2] Belluccia, D., Solaa, A., Gazzarrib, M., Chiellinib, F. and Cannilloa, V., 2013, A New Hydroxyapatite-Based Biocomposite for Bone Replacement, Mater. Sci. Eng: C, Vol. 33, No. 3, pp.1091-1101.

Google Scholar

[3] Flores, J.C., Cabrera, B.E., Calderon, T., Munoz, P.E., Adem, E., Hernandez, A.J., Boldu, J.L., Ovalle, M.P. and Murrieta, S.H., 2000, ESR and Optical Absorbtion Studies of Gamma- and Electron-irradiated Sugar Crystals, Appl. Radiat. Isotopes, Vol. 52, pp.1229-1234.

DOI: 10.1016/s0969-8043(00)00076-2

Google Scholar

[4] Da Costa, Z.M., Pontuschka, W.M. and Campos, L.L., 2004, Study of the ESR Signal of Gamma Irradiated Hydroxapatite for Dose Assessment, Nucl. Instrum. Meth. B, Vol. 218, pp.283-288.

Google Scholar

[5] Pankaew, P., Hoonnivathana, E., Limsuwan, P. and Naemchanthara, K., 2010, Temperature Effect on Calcium Phosphate Synthesized from Chicken Eggshells and Ammonium Phosphate, J. Appl. Sci., Vol. 10, No. 24, pp.3337-3342.

DOI: 10.3923/jas.2010.3337.3342

Google Scholar

[6] Sato, H., Filas, Benjamen, A., Eaton, Sandra, S., Eaton, Gareth, R., Romanyukha, Alex, A., Hayes, R. and Rossi, Alexandre, M., 2007, Electron Spin Relaxation of Radicals in Irradiated Tooth Enamel and Synthetic Hydroxyapatite, Radiat. Meas., Vol. 42, pp.997-1004.

DOI: 10.1016/j.radmeas.2007.05.048

Google Scholar

[7] Ikeya, M., 1993, New Applications of Electron Spin Resonance Dating, Dosimetry and Microscopy, World Scientific Publishing Co. Pte. Ltd., Singapore, 232-233.

DOI: 10.1007/bf03162626

Google Scholar

[8] Wencka, M., Hoffmann, S.K. and Hercman, H., 2005, EPR Dating of Hydroxyapatite from Fossil Bones Transient Effects after γ and UV Irradiation, Acta Phys. Pol. A, Vol. 108, No. 2, pp.331-337.

DOI: 10.12693/aphyspola.108.331

Google Scholar