Cellulose Hydrolysis by Acidic Ionic Liquids Enhanced with Microwave Heating

Hai Yun Ma; Zhi Ping Zhao; Peng Lu

doi:10.4028/www.scientific.net/AMR.1145.75

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1145Cellulose Hydrolysis by Acidic Ionic Liquids...

Cellulose Hydrolysis by Acidic Ionic Liquids Enhanced with Microwave Heating

Abstract:

The hydrolysis of cellulose into platform compounds and chemicals fuels has gained much attention to relieve the global energy crisis and environmental pollution. The filter paper (FP) cellulose with average degree of polymerization (DP) of 1000-1300 was dissolved in 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) firstly. And then acidic ionic liquids (ILs), ([(CH₂)₃SO₃HVIm]HSO₄) as the catalyst was applied to hydrolyze the FP cellulose by microwave heating. Compared with the oil bath heating method, microwave heating could effectively increase the total reducing sugars (TRS) yield about 10.7%. When the ratio of ILs catalyst to FP (w/w) was 0.167, and the ratio of deionized water to FP (w/w) was 0.833, the TRS yield was up to 60.8% within 20 min at 100°C.

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Advanced Materials Research (Volume 1145)

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75-79

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https://doi.org/10.4028/www.scientific.net/AMR.1145.75

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Online since:

March 2018

Authors:

Hai Yun Ma, Zhi Ping Zhao*, Peng Lu

Keywords:

Acidic Ionic Liquids, Catalytic Hydrolysis, Cellulose, Microwave Heating

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References

[1] A. N. Menegaki, K. P. Tsagarakis, Rich enough to go renewable, but too early to leave fossil energy?, Renew. Sustain, Energy Rev. 41 (2015) 1465-1477.

DOI: 10.1016/j.rser.2014.09.038

Google Scholar

[2] C. E. Wyman, B. E. Dale, R. T. Elander, et al., Coordinated development of leading biomass pretreatment technologies, Bioresour Tech. 96 (2005) 1959-(1966).

DOI: 10.1016/j.biortech.2005.01.010

Google Scholar

[3] Y. Nishiyama, P. Langan, H. Chanzy, Crystal structure and hydrogen-bonding system in cellulose Ib from synchrotron X-ray and neutron fiber diffraction, J. Am. Chem. Soc. 124 (2002) 9074-9082.

DOI: 10.1021/ja0257319

Google Scholar

[4] R. P. Swatloski, S. k. Spear, J. D. Holbrey, et a1., Dissolution of cellose with ionic liquids, J. Am. Chem. Soc. 124 (2002) 4974-4979.

DOI: 10.1021/ja025790m

Google Scholar

[5] Y. Liu et al., SO3H-functionalized acidic ionic liquids as catalysts for the hydrolysis of cellulose, Carbohydr. Polym. 92 (2013) 218–222.

DOI: 10.1016/j.carbpol.2012.08.095

Google Scholar

[6] K. Zhuo, Q. Du, G. Bai, et a1., Hydrolysis of cellulose catalyzed by novel acidic ionic liquids, Carbohydr. Polym. 115 (2015) 49-53.

DOI: 10.1016/j.carbpol.2014.08.078

Google Scholar

[7] Z. P. Zhao, X. L. Wang, G. Y. Zhou, Y. Cao, P. Lu, W. F. Liu, Hydrolysis kinetics of inulin by imidazole-based acidic ionic liquid in aqueous media and bioethanol fermentation, Chem. Eng. Sci. 151 (2016) 16-24.

DOI: 10.1016/j.ces.2016.05.017

Google Scholar

[8] G. L. Miller, Use of dinitrosalicyclic reagent for determination of reducing sugar, Anal. Chem. 31 (1959) 426–428.

DOI: 10.1021/ac60147a030

Google Scholar