The Synthesis and Characterization of Polyether-Modified Polysiloxane Phosphate

Abstract:

In order to combine the properties of phosphate surfactants and silicone surfactants, the polyether-modified polysiloxane phosphate (PPSP) was prepared. Firstly, the intermediate was synthesized through the hydrosilylation of hydricpolysiloxane and alkyl polyether. Then the polyether-modified polysiloxane phosphate was prepared through the phosphorylation reaction of intermediate and P2O5. The optimum condition of the phosphorylation reaction was the reaction temperature was 80°C, reaction time was 3.5h and molar ratio of -OH: P2O5 was 3.0:1.0. The molecular structure of phosphate was characterized by FTIR and 31P-NMR. The components and their capabilities were also studied. The CMC of PPSP was 0.58g/L and the surface tension related was 25.78mN/m, but the foaming power of PPSP is relatively low.

• Periodical: Advanced Materials Research (Volumes 129-131)
• Pages: 285-289
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.129-131.285
• Online since: August 2010
• Authors: Long Fang Ren, Xue Chuan Wang, Jian Hua Ding
• Keywords: Polyether-Modified Polysiloxane Phosphate, Surface Properties, Synthesis

References

[1] Kefeng S, Hong Y, Zhirong C. China Surfactant Detergent &Cosmetics Vol. 31(2001), p.34.

[2] Xuechuan W, Mingrang Z. Leather Science and Engineering Vol. 12(2002), p.26.

[3] O'LENICKA. U.S. Patent 5, 070, 171, 3(1991).

[4] O'LENICKA. U. S. Patent 5, 149, 765, 22(1992).

[5] Xue chuan W, Gu xia W. China leather Vol. 36(2007), p.57.

[6] Qiyu T, Haicheng W. Contemporary Chemical Industry Vol. 34(2005), p.284.

[7] Xin T, Wenzeng D. Textile Auxiliaries Vol. 17(2000), p.29.

[8] lin L, Jian hua Q, Chongmin Z. Speciality petrochemicals (1999), p.45.