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Kinetics of Mg2Sn Synthesis Reaction under Isothermal Condition
Abstract:
The kinetics of Mg2Sn synthesis reaction was studied under isothermal condition in the present paper. Results indicated that the isothermal reaction of Mg2Sn was controlled by two reactive mechanisms: the nucleation and growth control in the first stage corresponding to the Avrami exponent, m≈3, and the phase boundary control in the second stage corresponding to m≈1.1. The reactive activation energy (Ea ) for the two stages was 293.6 kJ·mol-1 and 358.1 kJ·mol-1, respectively. The microstructural evolution in Mg2Sn synthesis process was in good agreement with the two reactive mechanisms.
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1712-1716
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October 2010
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© 2011 Trans Tech Publications Ltd. All Rights Reserved
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