Kinetics of Mg2Sn Synthesis Reaction under Isothermal Condition

Article Preview

Abstract:

The kinetics of Mg2Sn synthesis reaction was studied under isothermal condition in the present paper. Results indicated that the isothermal reaction of Mg2Sn was controlled by two reactive mechanisms: the nucleation and growth control in the first stage corresponding to the Avrami exponent, m≈3, and the phase boundary control in the second stage corresponding to m≈1.1. The reactive activation energy (Ea ) for the two stages was 293.6 kJ·mol-1 and 358.1 kJ·mol-1, respectively. The microstructural evolution in Mg2Sn synthesis process was in good agreement with the two reactive mechanisms.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 146-147)

Pages:

1712-1716

Citation:

Online since:

October 2010

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K. Ishikawa, H. Watanabe and T. Mukai: Mater. Lett. Vol. 59 (2005), p.1511.

Google Scholar

[2] C.R. Clark, C. Wright, C. Suryanarayana, E.G. Baburaj and F.H. Froes: Mater. Lett. Vol. 33 (1997), p.71.

Google Scholar

[3] C.L. Mendis, C.J. Bettles, M.A. Gibson and C. Hutchinson: Mater. Sci. Eng.A. Vol. 435-436 (2006), p.16.

Google Scholar

[4] D.H. Kang, S.S. Park and N.J. Kim: Mater. Sci. Eng.A. Vol. 413-414 (2005), p.555.

Google Scholar

[5] Y. Zhang, X.L. Jiang, Y. Guan and A.N. Zheng: Mater. Lett. Vol. 59 (2005), p.3626.

Google Scholar

[6] S. Malinov,Z. Guo,W. Sha and A. Wilson: Metall. Mater. Trans.A. Vol. 32 (2001), p.879.

Google Scholar

[7] S. Chen H.F. Braun and T.P. Papageorgiou: J. Alloys Compd. Vol. 351 (2003), p.7.

Google Scholar

[8] R.Z. Hu and Q.Z. Shi, in: Thermal Kinetics, Science Press, Beijing, (2001), in press. (In Chinese).

Google Scholar