Measuring and Modeling of Viscosities of Selected CaO-MgO-Al2O3-SiO2 Slags

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Viscosities of selected quaternary CaO-MgO-Al2O3-SiO2 slags have been measured by rotary cylinder method up to a temperature of 1875K. 9 slag compositions have been selected in the composition range 40.04-50.64 wt. % CaO, 6.40-7.12 wt. % MgO, 22.84-41.73 wt. % Al2O3 and 10.25-20.70 wt. % SiO2. The effect of increasing temperature was investigated and it was shown that viscosity decreased, as expected, with increasing temperature. The viscosity increases with increasing the ratios of CaO/Al2O3, and following by a decrease with further increasing the ratios of CaO/Al2O3. An application of Iida’s viscosity model has been made. The Iida model gave good consistency with the measured viscosity values.

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Advanced Materials Research (Volumes 152-153)

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782-790

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October 2010

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] E. F. Riebling: J. Chem. Phys. Vol. 44(1966), p.2857.

Google Scholar

[2] B. O. Mysen, D. Virgo and I. Kushiro: Amer. Mineral. Vol. 66(1981), p.678.

Google Scholar

[3] J. B. Murdoch, J. F. Stebbins and I. S. E. Carmichael: Amer. Mineral. Vol. 70(1985), p.332.

Google Scholar

[4] B. Mysen: Structure and properties of silicate melts (Elsevier Science, Amsterdam 1988).

Google Scholar

[5] Q. F. Shu: Steel Research Int., Vol. 80(2009): p.107.

Google Scholar

[6] Z. T. Zhang, G. H. Wen, P. Tang, and S. Sridhar, ISIJ Int. Vol. 48(2008), p.739.

Google Scholar

[7] S. Seetharaman, S. Du. and F. Ji: Metall. Mater. Trans. B Vol. 31(200), p.105.

Google Scholar

[8] A. Kondratiev, P.C. Hayes, and E. Jak, ISIJ Int Vol. 46(2006), pp.359-367.

Google Scholar

[9] A. Kondratiev, P.C. Hayes, and E. Jak, ISIJ Int 2006. Vol. 46(2006), p.368.

Google Scholar

[10] A. Kondratiev, P.C. Hayes, and E. Jak, ISIJ Int 2006. Vol. 46(2006), p.375.

Google Scholar

[11] L Zhang and S. Jahanshahi: Metall. Mater. Trans. B, Vol. 29(1998), p.177.

Google Scholar

[12] L Zhang and S. Jahanshahi, Metall. Mater. Trans. B, Vol. 29(1998), p.187.

Google Scholar

[13] G. Urbain: J. Mater. Edu. Vol. 7(1985), p.1007.

Google Scholar

[14] G. Urbain: Steel Res., Vol. 58(1987), p.111.

Google Scholar

[15] P. Richet: Geochem. Cosmochim. Acta, Vol. 48(1984), p.471.

Google Scholar

[16] P. V. Riboud, Y. Roux, D. Lucas and H. Gaye: Fachber. Huttenprax. Metallweiterverarb. Vol. 19(1981), p.859.

Google Scholar

[17] T. Iida, S. Hidenori, Y. Kita, and S Koichi, ISIJ Int. Vol. 40(2000), pS1104.

Google Scholar

[18] K.C. Mills, and S. Sridhar, Ironmaking & Steelmaking,. Vol 26(1999), p.262.

Google Scholar

[19] N. Saito, M. Hori, K. Nakashima, and K. Mori: Metall. Mater. Trans. B Vol. 34(2003), p.509.

Google Scholar

[20] G. Hofmaier: Berg Huttenm. Monatsh. Montan. Hochschule Loeben Vol. 113(1968), p.270.

Google Scholar

[21] G. Urbain: Rev. Int. Haut. Temp. Refract. vol. 20(1983), p.135.

Google Scholar

[22] J. H. Park, .J. Min, and H.S. Song: Metall. Mater. Trans. B Vol. 35(2004), p.269.

Google Scholar

[23] J. S. Machin, T. B. Yee and D. L. Hanna: J. Am. Ceram. Soc. Vol. 35(1952), p.332.

Google Scholar

[24] P. Kozakevitch: Rev. Metall. Vol. 57(1960), p.149.

Google Scholar

[25] W. GUTT and A. D. RUSSELL: Journal of materials science Vol. 12(1977) p.1869.

Google Scholar

[26] S. Wright, L. Zhang, S. Sun, and S. Jahanshahi: Metall. Mater. Trans. B Vol. 31(2000), p.97.

Google Scholar

[27] S. Sridhar: JOM, Vol. 54(2002), p.46.

Google Scholar

[28] T. Iida and Y. Kita: report of the ISIJ meeting Vol. 15(2002), p.203.

Google Scholar

[29] L. Forsbacka, L. Holappa, T. Iida, Y. Kita and Y. Toda: Scandinavian Journal of Metallurgy Vol. 32(2003), p.273.

Google Scholar

[30] G. J. Jans: Molten salts handbook (Academic Press, New York 1967).

Google Scholar

[31] K. Nakajuma: Tetsu to Hagane Vol. 80(1994), p.593.

Google Scholar

[32] I. Barin: Thermochmical data of pure substances (VCH Verlag GmbH, Winheim 1989).

Google Scholar

[33] D. R. Lide: CRC Handbook of chemistry and physics. (CRC Press, Boca Raton 1998).

Google Scholar

[34] G. V. Somsonov: Fiziko-khimicheskie Svoistva Okislov (Metallurgiya, Moskva 1969).

Google Scholar

[35] N. Ikemiya, S. Umemoto, S. Hara and K. Ogino: ISIJ Int. Vol. 33(1993), p.156.

Google Scholar

[36] E. T. Turkdogan: Physicochemical properties of molten slags and glasses (The Metals Society, London 1983).

Google Scholar