Color Locating of Ce3+ and Eu2+ Doped Calcium Magnesium Chlorosilicate UV-LED Phosphors

Article Preview

Abstract:

Color coordinates (0.1573, 0.0528) and (0.1542, 0.4663) have been identified in Ce3+ and Eu2+ singly doped calcium magnesium chlorosilicate (CMSC) phosphors, which present the purplish-blue and green lights under ultraviolet (UV) radiation, respectively. In Ce3+/Eu2+ co-doped CMSC phosphors, with sensitizing the green emission of Eu2+, Ce3+ co-doping changed the luminescence color from green to bluish-green, presenting a preferable mixed effect from two primary colors. Potential mixture of red phosphors will provide the possibility in achieving the ideal white fluorescence under UV-LED excitation.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

16-20

Citation:

Online since:

March 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. Nakamura, T. Mukai and M. Senoh: Appl. Phys. Lett. Vol. 64 (1994), p.1687.

Google Scholar

[2] P. Schlotter, J. Baur, C.H. Hielscher, M. Kunzer, H. Obloh, R. Schmidt and J. Schneider: Mater. Sci. Eng. Vol. B59 (1999), p.390.

Google Scholar

[3] R.J. Yu, J. Wang, J.H. Zhang, H.B. Yuan and Q. Su: J. Solid State Chem. Vol. 181 (2008), p.658.

Google Scholar

[4] Y.C. Liao, C.H. Lin and S.L. Wang: J. Am, Chem. Soc. Vol. 127 (2005), p.9986.

Google Scholar

[5] Y. Gong, Y.H. Wang, Z.Q. Jiang, X.H. Xu and Y.Q. Li: Mater. Res. Bull. Vol. 44 (2009), p. (1916).

Google Scholar

[6] J.K. Park, K.J. Choi, C.H. Kim, H.D. Park and S.Y. Choi: Electrochem. Solid State Lett. Vol. 7 (2004), p. H15.

Google Scholar

[7] H.A. Hoppe, H. Lutz, P. Morys, W. Schnick and A. Seilmeier: J. Phys. Chem. Solids Vol. 61 (2000), p. (2001).

Google Scholar

[8] M. Yamada, T. Naitou, K. Izuno, H. Tamaki, Y. Murazaki, M. Kameshima and T. Mukai: J. Appl. Phys. Vol. 42 (2003), p. L20.

DOI: 10.1143/jjap.42.l20

Google Scholar

[9] X. Piao, T. Horikawa, H. Hanzawa and K. Machida: Appl. Phys. Lett. Vol. 88 (2006), p.161908.

Google Scholar

[10] H.C. Yang, Y. Liu, S. Ye and J.R. Qiu: Chem. Phys. Lett. Vol. 451 (2008), p.218.

Google Scholar

[11] A.A. Setlur, W.J. Heward, Y. Gao, A.M. Srivastava, R.G. Chandran and M.V. Shankar: Chem. Mater. Vol. 18 (2006), p.3314.

Google Scholar

[12] C.M. Zhang, J. Yang, C. K. Lin, C.X. Li and J. Lin: J. Solid State Chem. Vol. 182 (2009), p.1673.

Google Scholar

[13] Y. Pan, M. Wu and Q. Su: J. Phys. Chem. Solids. Vol. 65 (2004), p.845.

Google Scholar

[14] R.M. Mach, G. Mueller, M.R. Krames, H.A. Hoppe, F. Standler, W. Schnick, T. Juestel and P. Schmidt: Phys. Status Solidi. Vol. 202 (9) (2005), p.1727.

DOI: 10.1002/pssa.200520045

Google Scholar

[15] Y.S. Lin and R.S. Liu: J. Lumin. Vol. 122 (2007), p.580.

Google Scholar

[16] Y.B. Chen, M.L. Gong, G. Wang and Q. Su: Appl. Phys. Lett. Vol. 91 (2007), p.071117.

Google Scholar

[17] Y. Umetsu, S. Okamoto and H. Yamamoto: J. Electrochem Soc. Vol. 155 (2008), p. J193.

Google Scholar

[18] Q. Zeng, H. Tanno, K. Egoshi, N. Tanamachi and S. Zhang: Appl. Phys. Lett. Vol. 88 (2006), p.051906.

DOI: 10.1063/1.2168492

Google Scholar

[19] Z. Xia, Q. Li and J. Sun: Mater. Lett. Vol. 61 (2007), p.1885.

Google Scholar

[20] J. Liu, H. Lian, J. Sun and C. Shi: Chem. Lett. Vol. 34 (2005), p.1340.

Google Scholar

[21] T. Hou, D.W. He and D. Zhou: J. Chin. Chem. Soc. Vol. 34 (2006), p.1452.

Google Scholar

[22] P. Yang, J.H. Lin and G.Q. Yao: J. Rare Earths Vol. 23 (2005), p.633.

Google Scholar

[23] X. Zhang and X.R. Liu: J. Electrochem. Soc. Vol. 139 (1992), p.622.

Google Scholar

[24] H. Lin, X.R. Liu and E.Y.B. Pun: Optic. Mater. Vol. 18 (2002), p.397.

Google Scholar

[25] Y. Fang, W.D. Zhuang, Y.S. Hu, X.Y. Ye and X.W. Huang: J. Alloys Compd. Vol. 455 (2008), p.420.

Google Scholar

[26] H.S. Kang, S.K. Hong, H.Y. Koo, S.H. Ju, Y.C. Kang, K.Y. Jung and S.B. Park: J. Appl. Phys. Vol. 45 (2006), p.1617.

Google Scholar

[27] H.Y. Koo, J.M. Han and Y.C. Kang: J. Appl. Phys. Vol. 47 (2008), p.163.

Google Scholar