Chloromethylation Research of LX-1180 Macroporous Adsorption Resin in Ultrasonic Environment

Article Preview

Abstract:

This work performed the chloromethylation study of LX1180 in an ultrasonic environment, and presented a novel method to realize high chloromethylation degree for high crosslinking MARs. During this process, Monochloromethyl ether and anhydrous zinc chloride was adopted as chloromethylation reagent and catalyst respectively, the influences of conditions on the chloromethylation degree were investigated and optimized systemically. The sample prepared under the optimization conditions possessed the chloromethylation degree of 2.87 mmol/g.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 233-235)

Pages:

2893-2897

Citation:

Online since:

May 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J.C. Zhou, D.W. Feng, G.S. Zheng: J. Food Eng. Vol. 100( 2010), pp.289-293

Google Scholar

[2] L. Chao, Z. Hong, Z. Li, Z. Gang: Can. J. Chem. Eng. Vol. 88 (2010) pp.417-424

Google Scholar

[3] F.X. Zhang, Z. Wang, S.Y. Xu: Food Chem. Vol. 117 (2009), pp.387-392

Google Scholar

[4] F. Bai, B. Huang, X.L. Yang, W.Q. Huang: Polymer Vol. 48 (2007), pp.3641-3649

Google Scholar

[5] Y.N. Li, L.H. Yin, L.N. Xu, J.Y. Peng: J. Sep. Sci. Vol. 33 (2010), pp.2168-2175

Google Scholar

[6] B.L. He, Z.Q. Shi, X.Q. Guo, S.Y. Zhao: Chin. J. Polym. Sci. Vol. 2 (1986), pp.157-164

Google Scholar

[7] C.T.L. Luz, F.M.B. Coutinho: Polymer Vol. 42 (2001), p.4931.

Google Scholar

[8] Z.Q. Shi, R.F. Shi: application of adsorption separation macroporous adsorption resin in the pharmaceutical industry (Chemical Industry Publishing House, Chinese 2008)

Google Scholar

[9] F. Dong, Z.B. Chen, D.L. Di, L. Kang: Fine Chem. In Chinese Vol. 27, (2010), pp.760-764

Google Scholar

[10] Z.B. Chen, A.J. Zhang, J. Lei, F. Dong, D.L. Di, Y.Z. Wu: J. Phys. Chem. B Vol. 114 (2010), p.4841–4853

Google Scholar

[11] J.H. Huang, K.L. Huang, S.Q. Liu, Q. L, S.Y. Shi: J. Colloid Interface Sci. Vol. 317 (2008), pp.434-441

Google Scholar

[12] K.S. Wang, X.K. Dou: Polymer Physics (The Sci. Publishing Company, Chinese 2008)

Google Scholar

[13] D.T. Zhao, P. Wang, Y.C. Li, Z. Wang: Pharm. Biotechnol. In Chinese. Vol. 15 (2008), pp.231-234.

Google Scholar

[14] G.B. Rong, L.B. Yuan, Y. Yang: advanced organic chemistry (ECUST Press, Chinese 2007).

Google Scholar