Synthesis and Optoelectronic Properties of a New Photochromic Diarylethene Bearing a Cyano Group

Zhi Peng Tong; Shou Zhi Pu; Shi Qiang Cui; Wei Jun Liu

doi:10.4028/www.scientific.net/AMR.239-242.2419

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 239-242Synthesis and Optoelectronic Properties of a New...

Synthesis and Optoelectronic Properties of a New Photochromic Diarylethene Bearing a Cyano Group

Abstract:

A newunsymmetrical photochromic diarylethene 1-(2-cyanophenyl)-2-[2-methy-5-(3-fluorophenyl)-3-thienyl]perfluorocyclopentene (1a) has been synthesized. Its photochromic properties in solution and PMMA film were investigated. Diarylethene 1a changed the color from colorless to purple upon irradiation with 297 nm UV light, in which absorption maxima were observed at 540 nm in hexane and at 545 nm in PMMA film, respectively. This new photochromic system also exhibited remarkable fluorescence switching in the solid state. The results demonstrated that it can be potentially used as polarization holographic optical recording medium.

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Periodical:

Advanced Materials Research (Volumes 239-242)

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2419-2422

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.239-242.2419

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Online since:

May 2011

Authors:

Zhi Peng Tong, Shou Zhi Pu, Shi Qiang Cui, Wei Jun Liu

Keywords:

Diarylethene, Fluorescence Switching, Optical Storage, Photochromism

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