Paper Titles
Chitosan Cellulose Acetate Microspheres Preparation for Enhancement of Water-soluble Dye Adsorption
p.2855
The Activate Processe of Ni-P Electroless Plating on the Surface of SiC Particles
p.2859
SNOM Probe Based on Nano-Antenna with Large Aperture and High Resolution
p.2863
Research on the Key Technologies of Intelligent Control for Cap-Shape Bending of Sheet Metal
p.2867
A Novel Approach to Prepare Fluorinated Polyether Glycol Using Phase-Transfer Catalysts
p.2873
Synthesis、Structure and Catalytic Activity of TiO2/ La2Zr2O7 Nanocomposites
p.2878
Preparation and Fluorescence Properties of Dendritic 8-Hydroxyquinoline and their Zinc Complexes
p.2882
Effect of Complex Agents on the Performance of Electrodeposited Ni-Graphite Composites
p.2888
Novel Concept of Cleansing the Liquid Steel by the Fine In-Situ Phase due to the Composite Ball Explosion Reaction in RH Ladle
p.2895

A Novel Approach to Prepare Fluorinated Polyether Glycol Using Phase-Transfer Catalysts

Article Preview

Abstract:

The goal of this work has been the synthesis of novel fluorine-containing glycidyl ether based on 3, 3, 2, 2-tetrafluoropropanol (TFP) and epichlorohydrin (ECH) as the starting materials under condition of TBAB (Tetrabutylammonium bromide) catalyst. Furthermore, a novel fluorinated polyether glycol was successfully produced by the above synthesized fluorine-containing glycidyl ether. The structure of the products was characterized by 1H-NMR and IR spectrum. The number average molecular weight was measured by GPC.

You might also be interested in these eBooks
Advanced Materials, CEAM 2011 View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 239-242)

Pages:

2873-2877

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.239-242.2873

Citation:

Cite this paper

Online since:

May 2011

Authors:

Ying Li, Wei Song, Xia Wang

Keywords:

Epichlorohydrin, Fluorinated Polyether Glycol, Glycidyl Ether, Tbab

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] Matuszczak, S. and Feast, W. J.:J. Fluorine Chem., 2000, vol. 102, p.269.

Google Scholar

[2] Vatsuro, K.V. and Mishchenko, G.L.: Imennye reaktsiiv organicheskoi khimii (Named Reactions in Organic Chemistry), Moscow: Khimiya, 1976, p.403.

Google Scholar

[3] Li Ji ming, Wang Xia, Song Ai-ten, Yu Zhi-zhao: Synthesis of octyl glycidyl ether-a reactives diluent for epoxy resin. Thermosetting Resin, 1992, (1): 7-10.

Google Scholar

[4] Jiang Wei he, Qu Kai jia, Tang Zhaolan: Preparation of 1,2-cyclohexanediol diglycidyle. Thermosetting Resin,2004,Vol.19, pp.8-12.

Google Scholar

[5] C.M. Starks, M. Liotta, M. Halpern: Phase Transfer Catalysis: Fundamentals, Applications and Perspectives, Chapman and Hall, New York, 1994.

Google Scholar

[6] Y. Sasson, R. Neumann (Eds.): Handbook of Phase Transfer Catalysis, Blackie Academic and Professional, London, 1997.

Google Scholar

[7] G.D. Yadav, Topics Catal. 29 (2004) 145–161.

Google Scholar

[8] Petrov, V.A., J. Fluorine Chem., 2004, vol. 125, p.531

Google Scholar

[9] D.N. Bazhin, T.I. Gorbunova, A.Ya.Zapevalov, V.E. Kirichenko, and V.I. Saloutin: Features of Reaction between Fluorine-Containing Glycidyl Ethers and Alcohols in Basic Medium. Russian Journal of Organic Chemistry, 2007, vol.43, No.5, P.656-659.

DOI: 10.1134/s1070428007050041

Google Scholar

[10] I. Cho.: Polym. Sci. 25 (2000) 1043-1087.

Google Scholar