Characterization of (ENR-50)-Ionic Liquid Based Electrolyte System

Norazlin Zainal; Razali Idris; Mohamed Nor Sabirin

doi:10.4028/www.scientific.net/AMR.287-290.424

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 287-290Characterization of (ENR-50)-Ionic Liquid Based...

Characterization of (ENR-50)-Ionic Liquid Based Electrolyte System

Abstract:

Ionic liquid based on imidazolium cation; 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMITFSI) has been incorporated with epoxidized natural rubber-50 (ENR-50) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) to obtain electrolyte material. Fourier transform infrared spectroscopy (FTIR) spectra showed evidence of complexation between ENR-50, EMITFSI and LiTFSI. Glass transition temperature, T_g displayed an increasing trend with increase in salt concentration. The incorporation of EMITFSI resulted in an increase in ionic conductivity. The increase in ionic conductivity was attributed to the role of ionic liquid which reduced T_g, thus, facilitated ion conduction in the system. The highest ionic conductivity at room temperature was 5.72 ´ 10^-4 S cm^-1 for sample containing 20 wt% of EMITFSI and 50 wt% of LiTFSI.

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Periodical:

Advanced Materials Research (Volumes 287-290)

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424-427

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.287-290.424

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Online since:

July 2011

Authors:

Norazlin Zainal, Razali Idris, Mohamed Nor Sabirin

Keywords:

Conductivity, Epoxidized Natural Rubber (ENR), Ionic Liquid (IL)

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References

[1] N. Mohamed, N.A. Johari, A.M.M. Ali, M.K. Harun and M.Z.A. Yahya: J. Power Sources Vol 183 (2008), p.351

Google Scholar

[2] I. Razali and W.A.H. Wan Siti Nor: Solid State Science and Technology Vol 15(1) (2007), p.147

Google Scholar

[3] H.S. Kim, R. Idris and S.I. Moon: Bulletin of Electrochemistry Vol 20 (2004), p.465

Google Scholar

[4] J.H. Shin, W.A. Henderson, and S. Passerini: Electrochem. Commun. 5 (2003), p.1016

Google Scholar

[5] D.R. Macfarlane, M. Forsyth, P.C. Howlett, J.M Pringle, J. Sun, G. Annat, W. Neil, and E.I. Izgorodina: Acc. Chem. Res. Vol 40 (2007), p.1165

DOI: 10.1021/ar7000952

Google Scholar

[6] Y.S. Fung and R.Q. Zhou: J. Power Sources, Vol 81 (1999), p.891

Google Scholar

[7] R.C. Agrawal and G.P. Pandey: J. Phys. D:Appl. Phys. Vol 41 (2008), 223001.

Google Scholar

[8] H. Nakajima and H. Ohno: Polymer Vol 46 (2005), p.11499

Google Scholar

[9] M. Morita, T. Shirai, N. Yoshimoto and M. Ishikawa: J. Power Sources Vol 139 (2005), p.351

Google Scholar

[10] P. Bonhote, A.P. Dias, N. Papageorgiou, K. Kalyanasundaram and M. Gratzel: Inorg. Chem. Vol 35 (1996), p.1168

Google Scholar

[11] W. Lu, K. Henry, C. Turchi and J. Pellegrino: J. Electrochem. Soc. Vol 155 (2008), A361

Google Scholar

[12] N. Terasawa, I. Takeuchi, K. Mukai and K. Asaka: Polymer Vol 51 (2010), p.3372

Google Scholar

[13] J.H. Kim, B.R. Min, J. Won and Y.S. Kang: J. Phys. Chem. B Vol 107 (2003), p.5901

Google Scholar

[14] M.M. Armand, J.R. McCallum and C.A. Vincent: Polymer Electrolyte Reviews, Elsevier, London,(1987) vol. 1

Google Scholar