Synthesis and Characterization of Highly Regioregular Poly (3 - Hexylthiophene)

C.Y. Zhou; Lu Ting Yan; L.N. Zhang; X.D. Ai; T.X. Li

doi:10.4028/www.scientific.net/AMR.306-307.1649

Paper Titles

Grafting Sulfoammonium Zwitterionic Brushes onto Polycarbonateurethane Surface to Improve Hemocompatibility
p.1631

Electrochemical Properties of PANI/CNTs Composites Modified by Oxygen Plasma
p.1635

Fluorescent Sensors for Nitroaromatic Compounds Based on the Comb-Like Polysiloxane-Acrylate
p.1640

Flexible and Ordered Macroporous PMMA Polymers Films
p.1645

Synthesis and Characterization of Highly Regioregular Poly (3 - Hexylthiophene)
p.1649

Experimental Study on Uniaxial Time-Dependent Cyclic Deformation of POM/PTFE Blends
p.1653

Preparation of L-Tryptophan Imprinted Polymer Microspheres in Aqueous Media by In Situ Grafting on Surface
p.1658

The Properties and Hydrolysis of Polysiloxanes with Cyanoethyl Groups
p.1663

Synthesis and Application of Molecularly Imprinted Sol-Gel Film for Simultaneous Determination of Multi-Component Pesticide Residue
p.1667

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 306-307Synthesis and Characterization of Highly...

Synthesis and Characterization of Highly Regioregular Poly (3 - Hexylthiophene)

Abstract:

Regioregular poly (3-hexylthiophene) was synthesized by exchanging with Grignard agent followed by coupling with catalysis of Ni (dppp)Cl2. A nearly 100% HT-HT structure was verified from 1H-NMR and 13C-NMR data analysis. This highly regioregular structure gives P3HT outstanding stability and certain redshift of absorption spectra was found in contrast to materials with lower regioregularity.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 306-307)

Pages:

1649-1652

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.306-307.1649

Citation:

Cite this paper

Online since:

August 2011

Authors:

C.Y. Zhou, Lu Ting Yan, L.N. Zhang, X.D. Ai, T.X. Li

Keywords:

Poly(3-hexylthiophene), Regioregular, Synthesis

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] C.D. Dimitrakopoulos and P.R. L. Malenfant: AdV. Mater. Vol. 14 (2002), p.99.

Google Scholar

[2] K.M. Coakley and M.D. McGehee: Appl. Phys. Lett. Vol. 83 (2003), p.3380.

Google Scholar

[3] A.R. Murphy, J.S. Liu and C. Luscombe: Chem. Mater. Vol. 17 (2005), p.4892.

Google Scholar

[4] P.C. Shun: Study on the synthesis and characterization of regioregular poly (3-alkylthiophenes) and copolymers and application on organic field-effect transistor. 2006 THESIS, Tatung University.

Google Scholar

[5] A.B. Hugo and K.L. Christine: J. Am. Chem. Soc. Vol. 131 (2009), p.12894.

Google Scholar

[6] J.H. Tsai Y.C. Lai, T. Higashihara, C.J. Lin, M. Ueda and W.C. Chen: Macromolecules Vol. 43 (2010), p.6085.

Google Scholar

[7] D.M. Richard: Adv. Mater. Vol. 10 (1998), p.93.

Google Scholar

[8] R.M. Amanda, J.S. Liu, L. Christine, K. David, M.J.F. Jean, R. Joseph Kline and D.M. Michael: Chem. Mater. Vol. 17 ( 2005), p.4892.

Google Scholar

[9] H.Y. Chen, J.H. Hou, S.Q. Zhang, Y.Y. Liang, G.W. Yang, Y. Yang, L.P. Yu, Y. Wu and G. Li. Nature Photonics Vol. 3 (2009), p.649.

Google Scholar