Kinetics of the Adsorption for Naphthol Green by Epichlorohydrin Modified Peanut Shell

Article Preview

Abstract:

The adsorption of naphthol green by peanut shell, which was chemically-modified by cross-linking with epichlorohydrin was studied with variation in the parameters of contact time and temperature. They were used for equilibrium adsorption uptake studies with naphthol green. The results revealed that adsorption equilibriums were rapidly established in about 3h. Three different kinetic models (i.e.,intraparticular diffusion model, Lagergren-first-order and second-order equations) were used to describe the adsorption kinetic mechanisms. The adsorption of naphthol green on epichlorohydrin modified peanut shell(EMPS) was not controlled by intraparticular diffusion. The kinetic adsorption data can be well simulated by the second-order equation and the adsorption might be rate-limiting controlled. The suitability of the adsorbent was evaluated by fitting the equilibrium data with Langmuir and Freundlich isotherms, which gave good fits with both isotherms.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 311-313)

Pages:

1531-1534

Citation:

Online since:

August 2011

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M.Ozacar,A.Sengil:Environmental Geology,Vol.45(2004), p.762

Google Scholar

[2] J. X.Lin S.L. Zhan M.H. Fang X.Q. Qian:J.Porous Mater.,Vol14(2007),p.449

Google Scholar

[3] L.M. Soldatkina E.V. Sagaidak and V.V. Menchuk:Journal of Water Chemistry and Technology, Vol.31(2009),p.238

Google Scholar

[4] R.W. Gaikwad S.A.M. Kinldy: Korean J. Chem. Eng., Vol.26(2009),p.102

Google Scholar

[5] R.Gong,Y Sun,J Chen,et al.Dyes & Pigments,Vol.67(2005),p.175

Google Scholar

[6] O.Dursun,D.Gulbeyi,O.Ahmet.:Journal of Hazardous Materials.Vol. 144(2007),p.171

Google Scholar

[7] G.Mckay:The Chemical Engineering Journal.Vol.27(1983),p.187

Google Scholar

[8] W.J. Weber, J.C. Morriss,:J. Sanit. Eng. Div. Am. Soc. Civ. Eng.Vol.89(1963),p.31

Google Scholar

[9] S.Lagergren:Kungliga Svenska Vetensk. Handl.Vol.24(1898),p.1

Google Scholar

[10] Y.S.Ho, G.McKay:Process Biochem.Vol.34(1999),p.451

Google Scholar