TiC particulates reinforced iron matrix surface composite was produced by cast technique and in-situ synthesis technique. The surface composite was investigated from thermodynamics, microstructure, wear-resistance and oxidation-resistance. The results show TiC particles whose volume fraction is about 40% exhibit fine size in iron matrix on the surface composite. An excellent metallurgy-bond is observed between the surface composite and the gray iron. Fe-TiC surface composite shows good oxidation-resistance at 900°C and great wear-resistance under condition of dry sliding.