The Structure of Two-Dimensional Layered Cu (ΙΙ) Complex Material
A Cu (II) complex has been obtained by one-pot reaction of copper nitrate with 4-aminobenzene sulfonic acid, 2-acetylpyridine and sodium hydroxide. Unfortunately, the complex does not contain 2-acetylpyridine molecules, and 4-aminobenzene sulfonic acid coordinate to Cu (II) ion. The structure of Cu (II) complex was characterized by single-crystal X-ray diffraction. The results show that the complex crystallizes in monoclinic, space group P2(1)/n with a = 0.7437(3) nm, b = 1.7408(6) nm, c = 0.7644(3) nm, V = 0.8846(5) nm3, Z = 2, F (000) = 494, Rint = 0.0697, and the complex formed two dimensional layered structure through intramolecule and intermolecule hydrogen bonds and π-π stacking interaction.
Helen Zhang and David Jin
X. S. Tai "The Structure of Two-Dimensional Layered Cu (ΙΙ) Complex Material", Advanced Materials Research, Vol. 366, pp. 392-395, 2012