The Structure of Two-Dimensional Layered Cu (ΙΙ) Complex Material

Abstract:

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A Cu (II) complex has been obtained by one-pot reaction of copper nitrate with 4-aminobenzene sulfonic acid, 2-acetylpyridine and sodium hydroxide. Unfortunately, the complex does not contain 2-acetylpyridine molecules, and 4-aminobenzene sulfonic acid coordinate to Cu (II) ion. The structure of Cu (II) complex was characterized by single-crystal X-ray diffraction. The results show that the complex crystallizes in monoclinic, space group P2(1)/n with a = 0.7437(3) nm, b = 1.7408(6) nm, c = 0.7644(3) nm, V = 0.8846(5) nm3, Z = 2, F (000) = 494, Rint = 0.0697, and the complex formed two dimensional layered structure through intramolecule and intermolecule hydrogen bonds and π-π stacking interaction.

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Periodical:

Edited by:

Helen Zhang and David Jin

Pages:

392-395

DOI:

10.4028/www.scientific.net/AMR.366.392

Citation:

X. S. Tai "The Structure of Two-Dimensional Layered Cu (ΙΙ) Complex Material", Advanced Materials Research, Vol. 366, pp. 392-395, 2012

Online since:

October 2011

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$35.00

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