Steel Slag as Neutralization-Adsorption Material for Treatment of Acidic Zn2+ - Containing Wastewater

Article Preview

Abstract:

Chemical and mineral compositions, the surface morphology of steel slag were evaluated in this study. On this basis, treatment effect of acidic Zn2+-containing wastewater was investigated using the slag as a water treatment material, and then mechanism of removal Zn2+ was discussed. The results showed steel slag was a suitable material for treatment of acidic heavy mental wastewater. Under conditions of slag size fraction of -1.2+0.15mm, slag concentration of 30 g∙L-1, stirring speed of 150rpm for 30 min, removal rate of Zn2+ was 98.59%, Zn2+ concentration in wastewater was reduced from 100 mg/L to 1.41 mg/L, and pH value was increased from 2 to 6.4. Filtrate after treatment reached the first discharge standard in integrated wastewater discharge standard (GB8978-1996). Appearance of Zn (OH)2 diffraction peaks in XRD pattern showed that Zn (OH)2 had covered on steel slag surface, and Zn2+ removal included four main processes: production of OH- from hydration reaction of aSubscript textctive calcium silicate in steel slag, generation of Zn (OH)2 precipitation in wastewater, adsorption and settlement of Zn (OH)2 on surface of steel slag and removal of Zn (OH)2 from wastewater by filtration.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 383-390)

Pages:

3416-3421

Citation:

Online since:

November 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Zhigang Liu. Lime neutralization processed acid waste water containing heavy metal ions. Jiangxi Metallurgy, vol. 23, pp.109-110, Dec. 2003 (in Chinese).

Google Scholar

[2] Huifen Yang, Pingfeng Fu, Feng. Zhou. Adsorption and reduction of Cr (VI) in aqueous solution using steel slag particles. The Chinese Journal of Process Engineering, vol. 8, pp.499-503, Jun. 2008 (in Chinese).

Google Scholar

[3] N. Ortiz, M.A.F. Pires, J.C. Bressiani. Use of steel converter slag as nickel absorber to wastewater treatment. Waste Management, Vol. 21, pp.631-635, Jul. (2001).

DOI: 10.1016/s0956-053x(00)00123-9

Google Scholar

[4] D.H. Kim, M.C. Shin, H.D. Choi, et al. Removal mechanisms of copper using steel-making slag: adsorption and precipitation. Desalination, Vol. 223, p.283–289, Mar. (2008).

DOI: 10.1016/j.desal.2007.01.226

Google Scholar

[5] Shengyu Liu, Jin Gao, Yijin Yang, et al. Adsorption intrinsic kinetics and isotherms of lead ions on steel slag. Journal of Hazardous Materials, Vol. 173, p.558–562, Jan. (2010).

DOI: 10.1016/j.jhazmat.2009.08.122

Google Scholar

[6] Jibing Xiong, Zhenli He, Q. Mahmood, et al. Phosphate removal from solution using steel slag through magnetic separation. Journal of Hazardous Materials, Vol. 152, p.211–215, Mar. (2008).

DOI: 10.1016/j.jhazmat.2007.06.103

Google Scholar

[7] V.K. Jha, Y. Kameshima, A. Nakajima, et al. Utilization of steelmaking slag for the uptake of ammonium and phosphate ions from aqueous solution. Journal of Hazardous Materials, Vol. 156, p.156–162, Aug. (2008).

DOI: 10.1016/j.jhazmat.2007.12.009

Google Scholar

[8] Bhatnagar, A.K. Jain. A comparative adsorption study with different industrial wastes as adsorbents for the removal of cationic dyes from water. Journal of Colloid and Interface Science, Vol. 281, p.49–55, Jan. (2005).

DOI: 10.1016/j.jcis.2004.08.076

Google Scholar

[9] C.S. Gahan, M.L. Cunba, Å Sandström. Comparative study on different steel slags as neutralising agent in bioleaching. Hydrometallurgy, Vol. 95, p.190–197, Feb. (2009).

DOI: 10.1016/j.hydromet.2008.05.042

Google Scholar

[10] W. Cha, J. Kim, H. Choi. Evaluation of steel slag for organic and inorganic removals in soil aquifer treatment. Water Research, Vol. 40, pp.1034-1042, Mar. (2006).

DOI: 10.1016/j.watres.2005.12.039

Google Scholar

[11] J.S. Stolaroff, G.V. Lowry, D.W. Keith. Using CaO- and MgO-rich Industrial Waste Streams for Carbon Sequestration. Energy Conversion and Management, Vol. 46, pp.687-699, Mar. (2005).

DOI: 10.1016/j.enconman.2004.05.009

Google Scholar

[12] GB8978-1996, Integrated wastewater discharge standard (in Chinese).

Google Scholar