An Investigation of the Nano-Structure Titanum Dioxde Thin Films as a Function of Film Thickness

Article Preview

Abstract:

Using resistive heated method, Ti films of different thickness ranging from 10 to 200 nm were deposited and post-annealed at a temperature of 473K with a flow of oxygen. The optical properties were measured by transmission spectroscopy in spectral range of 200-2500 nm. The optical functions were obtained from the Kramers-Kronig analysis of the reflectivity curves. The effective medium approximation analysis was employed to establish the relationship between the nano-structure and Effective-Media Approximation (EMA) predictions.It was found the temperature of deposition and thefilm thickness play important roles in the nano-structure of the film and cause significant variations in the optical behaviour of thin Titanium oxide films.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 403-408)

Pages:

3-7

Citation:

Online since:

November 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] L. Kavan, M. Gratzel, Electrochim. Acta, 40 (1995) 643.

Google Scholar

[2] S. D. Burnside, V. Shklover, C. Barbe, Chem. Mater., 10 (1998) 2419.

Google Scholar

[3] P. Sawunyyama, A. Yasumori, m K. Okada, Mater. Res. Bull., 33 (1998) 795.

Google Scholar

[4] S. Deki, Y. Aoi, J. Mater. Res. 13 (1998) 883.

Google Scholar

[5] S. Yin, Y. Inoue, S. Uchida, Y. Fujishiro, T. Sato, J. Mater. Res., 13 (1998) 844.

Google Scholar

[6] E. Vigil, L. Saadoun, R. Rodriguez-Clemente, J. A. Ayllon, X. Domenech, J. Mater. Sci. Lett., 18 (1999) 1067.

DOI: 10.1023/a:1006691320224

Google Scholar

[7] H. Savaloni, K. Khojier, M. S. Alaee, J. Mater. Sci., 42 (2007) 2603.

Google Scholar

[8] K. A. Vorotilov, E. V. Orlova, V. I. Petrovsky, Thin Solid Films, 207 (1992) 180.

DOI: 10.1016/0040-6090(92)90120-z

Google Scholar

[9] M. G. Krishana, K. Narasimaha Rao, S. Mohan, J. Appl. Phys., 73 (1983) 434.

Google Scholar

[10] J. Rancourt, User's Handbook: Optical Thin Film, McGrow-Hill, New York, (1987).

Google Scholar

[11] J. A. Dobrowski, in: W. Driscoll (Ed. ), Coating and Filters in Handbook of Optics, MacGrow-Hill, New York, (1987).

Google Scholar

[12] P. Babelon, A. S. Dequiedt, H. Mostesa-Sba, S. Bourgeois, P. Sibillot, M. Sacilotti, Thin Solid Films, 322 (1998) 63.

DOI: 10.1016/s0040-6090(97)00958-9

Google Scholar

[13] Y. Leprince-Wang, K. -Y. Zhang, V. Nguyen, V. An, D. Souche, J. Rivory, Thin Solid Films, 307 (1997) 38.

DOI: 10.1016/s0040-6090(97)00293-9

Google Scholar

[14] B. O'Regan, M. Gratzel, Nature, 353 (1991) 737.

Google Scholar

[15] U. Bach, D. Lupo, P. Comte, J. E. Moser, F. Weissortel, J. Salbeck, H. Spreitzer,M. Gratzel, Nature, 395 (1998) 583.

Google Scholar

[16] L. Kavan, M. Gratzel, Electrochim. Acta, 40 (1995) 643.

Google Scholar

[17] R. L. Pozzo, M. A. Baltanas, A. E. Cassano, Catalysis Today, 39 (1997) 219.

Google Scholar

[18] T. -S. Kang, D. Kim, K. -J. Kim, J. Electrochem. Soc., 145 (1998) (1982).

Google Scholar

[19] Y. Paz, Z. Luo, L. Rabenberg, A. Heller, J. Mater. Res., 10 (1995) 2842.

Google Scholar

[20] Ida, T. & Toraya, H., J. Appl. Cryst. 35 (2002) 58.

Google Scholar

[21] M. Cernasky, J. Appl. Cryst. 16 (1983) 103.

Google Scholar

[22] R. W. Cheary and A. Coelho, J. Appl. Cryst. 25 (1992) 109.

Google Scholar

[23] D. Balzar and S. Popovic, J. Appl. Cryst. 29 (1996) 16.

Google Scholar

[24] D. Balzar, J. Appl. Cryst. 25 (1992) 559.

Google Scholar

[25] J. K. Yau and S. A. Howard, J. Appl. Cryst. 22 (1989) 244.

Google Scholar

[26] S. A. Howard, and R. L. Snyder, J. Appl. Cryst. 22 (1989) 238.

Google Scholar

[27] S. Enzo, G. Fagherazzi, A. Benedetti and S. Polizzi, J. Appl. Cryst. 22 (1989) 184.

Google Scholar

[28] H. Savaloni, A. Taherizadeh, A. Zendehnam, Physica B, 349 (2004) 44.

Google Scholar

[29] R. B. Johnson and R. W. Christy, Physical Review B, 9 (1974) 5056-5070.

Google Scholar

[30] D. W. Lynch, C. G. Olson, J. H. Weaver, Physical Review B, 11 (1975) 3617-3624.

Google Scholar

[31] W. E. Wall, M. W. Ribrasky and J. R. Stevenson, J. App. Phys, 51 (1980) 661-667.

Google Scholar

[32] E. Aspnes, Thin Solid Films, 89 (1982) 249.

Google Scholar

[33] D. A. G. Brauggeman, Ann. Phys. (Leipzig), 24 (1935) 636.

Google Scholar

[34] E. Aspnes, E. Kinsbron, and D. D. Bacon, Phys. Rev. B21 (1980) 3290.

Google Scholar

[35] R. Messier and J. E. Yahoda, J. Appl. Phys, 58 (1985) 3739.

Google Scholar

[36] P. B. Barna, M. Adamik, Thin Solid Films, 317 (1998) 27-33.

Google Scholar

[37] I. Petrov, P. B. Barna, L. Hultman, J. E. Greene, J. Vac. Sci. Technol, S117-S128.

Google Scholar