Effects of Solvents on the Electrical Resistance of Poly(3,4-ethylenedioxythiophene) on Textiles

Article Preview

Abstract:

The chemical resistance of Poly-3,4-ethylenedioxythiophene (PEDOT) was tested in both organic and inorganic solvents including Chloroform, DMSO, Xylene, THF, sulfuric acid, sodium hydroxide and sodium chloride. PEDOT was synthesized via the vapor-phase polymerization and coated on PET/cotton, cotton and polyester textile substrates. Electrical resistances of the PEDOT were measured both before and after chemical treatments. The morphological changes after treatments were studied by scanning electron microscope (SEM). The PEDOT coated fabrics demonstrated excellent chemical-resistant property since its electrical resistance maintained on the order of magnitude of 100 ohm after treatment in almost all the solvents except NaOH with which a remarkable increasing of electrical resistance occurred due to disappearing PEDOT from the substrate indicating its potential to be a good solvent for PEDOT.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

16-22

Citation:

Online since:

January 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] B. Winther-Jensen, K. West, Vapor-Phase Polymerization of 3, 4 Ethylenedioxythiophene: A Route to Highly Conducting Polymer Surface Layers, Macromolecules. 37 (2004) 4538-4543.

DOI: 10.1021/ma049864l

Google Scholar

[2] Catarina Carlberg, Xiwen Chen, Olle Inganas, Ionic Transport and Electronic Structure in Poly(3, 4-ethylene dioxythiophene), Solid State Ionics. 85 (1996) 73-78.

DOI: 10.1016/0167-2738(96)00043-4

Google Scholar

[3] Stephan Kirchmeyer and Knud Reuter, Scientific Importance, Properties and Growing Applications of Poly (3, 4-ethylenedioxythiophene), J. Mater. Chem. 15 (2005) 2077-(2088).

DOI: 10.1039/b417803n

Google Scholar

[4] Okan Ala and Qinguo Fan, Applications of Conducting Polymers in Electronic Textiles, RJTA. 13(2009).

Google Scholar

[5] J. Y. Kim, J. H. Jung, D. E. Lee, J. Joo. Enhancement of Electrical conductivity of Poly (3, 4-ethylen-edioxythio phene)/poly(4-styrenesulfonate) by a change of solvent, Synthetic Metals. 126 (2002) 311-316.

DOI: 10.1016/s0379-6779(01)00576-8

Google Scholar

[6] Leif A.A. Pettersson, Soumyadeb Ghosh and Olle Inganas, Optical Anistropy in Thin Films of Poly (3, 4-ethy lenedioxythiophene)-poly(4-styrenesulfonate), Org. Electron. 3 (2002) 143-148.

Google Scholar

[7] S.K.M. Jonsson, J. Birgerson, X. Crispin, G. Greczynski,W. Osikowicz, A.W. Denier van der Gon, W.R. Salaneck, M. Fahlman. The Effects of Solvents on the Morphology and Sheet Resistance in Poly (3, 4-ethylenedioxythiop hene)-polystrenesulfonic acid (PEDOT-PSS) Films, Synthetic Metal. 139 (2003).

DOI: 10.1016/s0379-6779(02)01259-6

Google Scholar

[8] Jianyong Ouyang, Qianfei Xu, Chi-Wei Chu, Yang Yang, Gang Li, Joseph Shinar, On the Mechanism of Conductivity Enhancementin poly (3, 4-ethylenedioxythiophene): poly(styrene sulfonate) Film through solvent treatment, Polymer. 45 (2004) 8443-8450.

DOI: 10.1016/j.polymer.2004.10.001

Google Scholar

[9] Toshimi Shimizu, Self-Assembled Nanomaterials II: Natubes, Springer, (2008).

Google Scholar