Stabilization of Natural Dyes by High Levels of Antioxidants

Article Preview

Abstract:

Natural dyes are normally unstable to photooxidation by UV light. We have measured the stability of a number of natural dyes in combination with high concentrations of antioxidants, excited state quenchers, and UV absorbers. We find that certain combinations, including indigo/BHT, methylene blue/p-benzoquinone, and methylene blue/triethylamine show enhanced stability in solution and/or in thin polymer films. By comparing solutions and films of the mixed components with solutions and films of the antioxidant placed between the dye and UV source, we can show that the effect is not UV screening but is due to some form of intermolecular chemistry. We believe that this effect may account for the high stability of natural dyes in plant tissues, such as the skins of fruit, and may be usable to stabilize natural dyes in foods or textiles, especially if suitable nanoparticle structures can be developed.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

192-199

Citation:

Online since:

January 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Scott, G., Photodegradation and photostabilization, Journal of Photochemistry. 25 (1984) 83-90.

Google Scholar

[2] D.M. Wiles and D.J. Carlsson, Photostabilization mechanisms in polymers - a review, Polymer Degradation and Stability. 3 (1980) 61-72.

DOI: 10.1016/0141-3910(80)90008-7

Google Scholar

[3] H.J. Heller and H.R. Blattmann, Some aspects of stabilization of polymers against light, Pure and Applied Chemistry. 36 (1973) 141-162.

DOI: 10.1351/pac197336010141

Google Scholar

[4] J.F. Mckellar and N.S. Allen (Eds. ), Photochemistry of man-made polymers, Applied Science Publishers LTD, (1979).

Google Scholar

[5] G. Scott, Antioxidant role of UV stabilizers, Pure and Applied Chemistry. 52 (1980) 365-387.

Google Scholar