Photocatalytic Degradation Kinetics of Reactive Red 3BS Using Ag Doped TiO2

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The photocatalyst of Ag doped TiO2 in liquid state was applied to decolorize the Reactive Red 3BS under UV irradiation. The rate of photocatalytic degradation of the dye was improved with increasing the concentration of catalyst from 1 g/L to 8 g/L. But as a result of light attenuation for the rising catalyst concentration, the rate of reaction was constant at 8-12 g/L of the catalyst concentration. The rate of dye photocatalytic degradation decreased with increasing initial concentration of dye. The kinetics of photocatalytic reaction was also studied. The results showed that degradation reaction is congruent with an apparent first-order kinetic equation, and the relationship between apparent reaction rate and initial dye concentration fits approximately a negative second-order kinetic relationship.

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598-602

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January 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Papić, N. Koprivanac and A. L. Boi, Removal of some reactive dyes from synthetic wastewater by combined Al(III) coagulation/carbon adsorption process, Dyes and Pigments. 62 (2004) 291-298.

DOI: 10.1016/s0143-7208(03)00148-7

Google Scholar

[2] P.C. Vandevivere, R. Bianchi, W. Verstraete, Treatment and reuse of wastewater from the textile wet-processing industry, review of emerging technologies, J. Chem. Tech. Biot. 72 (1998) 289-302.

DOI: 10.1002/(sici)1097-4660(199808)72:4<289::aid-jctb905>3.0.co;2-#

Google Scholar

[3] R. Jain, M. Shrivastava, Photocatalytic removal of hazardous dye cyanosine from industrial waste using titanium dioxide, J. Hazard. Mater. 152 (2008) 216–220.

DOI: 10.1016/j.jhazmat.2007.06.119

Google Scholar

[4] H. Gerixhac, Photoelectrochemical catalysis of the oxidation of organic molecules by oxygen on small semiconductor particles with TiO2, as an example, Electrochim. Acta. 38 (1993) 39-45.

DOI: 10.1016/0013-4686(93)80003-i

Google Scholar

[5] G. MST, O.C. AMF, P. EMMS, Photochemical treatment of solutions of azo dyes containing TiO2, Chemosphere. 39(1999) 781-786.

DOI: 10.1016/s0045-6535(99)00013-2

Google Scholar

[6] Y.Z. Li, X. Kong, Y.X. Zhou, Pilot research on the treatment of azo dye 4BS solution by a fluidized bed photocatalytic reactor. Enviromental Engineering. 21 (2003) 7-11.

Google Scholar