Influence of Reduction Time of SSI on Nitrite Removal from Wastewater

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Abstract:

Spherical sponge iron (SSI) with high activity and intension could be prepared through direct reduction by hydrogen. To optimize the reduction technology of SSI and its removal ability for nitrate from wastewater, the influence of reduction time of SSI on nitrate removal percentage was investigated. Because the specific surface area was impact smartly by the reduction time of SSI, it was suggested that nitrate removal ability of SSI should declined with the increasing of reduction time once the reduction time longer than the optimized reduction time. When the reduction time was t1, nitrate removal percentage reached to the maximum. When the nitrate original concentration was 5mg-N/L, the reaction order was closed to 0.7 and the apparent reaction rate constant was 0.323 to 0.359 h-1. When nitrate original concentration increased to 50 mg-N/L, nitrate removal reaction appeared to be the pseudo-first-order reaction, and the apparent reaction rate constant was 0.314 to 0.248 h-1.

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Advanced Materials Research (Volumes 450-451)

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667-671

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January 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Kumar, S. Chakraborty, Chemical denitrification of water by zero-valent magnesium powder. J Hazard. Mater., B135(2006), p.112.

Google Scholar

[2] G. C. C. Yang, H. L. Lee, Chemical reduction of nitrate by nanosized iron: kinetics and pathways. Water Res., 39(2005), p.884.

DOI: 10.1016/j.watres.2004.11.030

Google Scholar

[3] Y. P. Feng, J. G. Li, N. Bi, X. L. Yan, Static experimental research on nitrate reduction removal from water by spherical sponge iron. Environ. Sci. and Technol., 6(2008), p.14.

Google Scholar

[4] S. Choe, H. M. Liljestrand, J. Khim, Nitrate reduction by zero-valent iron under different pH regimes. Applied Geochem., 19(2004), p.335.

DOI: 10.1016/j.apgeochem.2003.08.001

Google Scholar

[5] A. Yazdankhah, S. E. Moradi, S. Amirmahmoodi, M. Abbasian, S. E. Shoja, Enhanced sorption of cadmium ion on highly ordered nanoporous carbon by using different surfactant modification. Microporous and Mesoporous Mater., 1(2010), p.35.

DOI: 10.1016/j.micromeso.2010.04.012

Google Scholar

[6] S. M. Ponder, J. G. Darab, T. E. Mallouk, Remediation of Cr(VI) and Pb(II) aqueous solutions using supported, nanoscale zero-valent iron. Environ. Sci. Technol., 12 (2000) 2564-2569.

DOI: 10.1021/es9911420

Google Scholar

[7] J. G. Li, J. Li, Y. G. Li, Cadmium removal from wastewater by sponge iron sphere prepared by charcoal direct reduction. J. Environ. Sci. suppl (2009), p.60.

DOI: 10.1016/s1001-0742(09)60038-3

Google Scholar

[8] J. G. Li, L. H. Wei, Y. G. Li, N. Bi, F. F. Song, Cadmium removal from wastewater by sponge iron sphere prepared by hydrogen reduction. J. Environ. Sci. suppl.(2011), p.114.

DOI: 10.1016/s1001-0742(11)61090-5

Google Scholar