Preparing CNT/UHMWPE Composite and it’s Electrical Property Study

Article Preview

Abstract:

Composite particles with ultra-high molecular polyethylene (UHMWPE) core and carbon nanotube (CNT) shell were produced by an impact coating process, and molded into conductive polymer composites. Morphology of these composite particles was observed and the electrical behavior of these molded composites was measured. UHMWPE particles were very well coated by CNT, and conductive networks of CNT were formed after molding. These conductive polymer composites with low loadings of conductive filler exhibit lower room-temperature resistivity, and volume resistivity decreases with temperature on the whole. This is because of the CNT distribution is uniform in a macroscopic view but is oriented in a mesoscopic view. Thermionic emission of CNT is strong in polymer composites produced by this process. A related mechanism is discussed.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

67-71

Citation:

Online since:

January 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] X.Wang, G.Zhang, PTC effect of carbon fiber filled EPDM rubber composite, J. Mater. Sci. Mater. Electron. Vol.19 (2008), p.1107

DOI: 10.1007/s10854-007-9476-1

Google Scholar

[2] X. Zhang, Y. Pan, Q. Zheng, et al. A new polymer composite thermistor having double PTC transitions, J. Appl. Polym. Sci. Vol.78 (2000), p.426

DOI: 10.1002/1097-4628(20001010)78:2<424::aid-app220>3.0.co;2-6

Google Scholar

[3] Z. Su, C. Li, The study of the super-stability of carbon filled PTC blends containing UHMWPE, Plastic Sci.& Tech. Vol.4 (2001), p.6

Google Scholar

[4] C. Chan, C. Cheng, Electrical properties of polymer composites prepared by sintering a mixture of carbon black and ultra-high molecular weight polyethylene powder. Polymer Engineering and Science. Vol.37 (1997), p.1127.

DOI: 10.1002/pen.11757

Google Scholar

[5] J. Zhang, Q. Zhang, Y. Yang, et al. High-density polyethylene/carbon black conductive composites. II. Effect of electron beam irradiation on relationship between resistivity-temperature behavior and volume expansion, J. Appl. Polym. Sci. Vol.83 (2002), p.3118.

DOI: 10.1002/app.10050

Google Scholar

[6] S.J. Park, H. C. Kim, H. Y. Kim, Roles of work of adhesion between carbon blacks and thermoplastic polymers on electrical properties of composites, J. Coll. Inter. Sci. Vol.255 (2002), p.145

DOI: 10.1006/jcis.2002.8481

Google Scholar

[7] M.O. Lisunova, Y.P. Mamunya, N.I. Lebovka, et al. Percolation behaviour of ultrahigh molecular weight polyethylene/multi-walled carbon nanotubes composites, European Polymer Journal, Vol.43 (2007), p.949

DOI: 10.1016/j.eurpolymj.2006.12.015

Google Scholar

[8] J.H. Lee, S.K. Kim, N.H. Kim, Effects of the addition of multi-walled carbon nanotubes on the positive temperature coefficient characteristics of carbon-black-filled high-density polyethylene nanocomposites, Scripta Materialia. Vol.55 (2006), p.1119

DOI: 10.1016/j.scriptamat.2006.08.051

Google Scholar

[9] S. Jiang, Y. Yu, J. Xie, et al, Positive temperature coefficient properties of multiwall carbon nanotubes/poly(vinylidene fluoride) nanocomposites, J. Appl. Polym. Sci. Vol.116 (2010), 838-842.

DOI: 10.1002/app.31569

Google Scholar

[10] I. Mironi-Harpaz, M.Narkis, Electrical behavior and structure of polypropylene/ultrahigh molecular weight polyethylene/carbon black immiscible blends, J. Appl. Polym. Sci. Vol.81 (2001), p.104

DOI: 10.1002/app.1419

Google Scholar

[11] C. Zhang, C. Ma, P. Wang, et al. Temperature dependence of electrical resistivity for carbon black filled ultra-high molecular weight polyethylene composites prepared by hot compaction, Carbon, Vol.43 (2005), p.2544

DOI: 10.1016/j.carbon.2005.05.006

Google Scholar

[12] R. Pfeffer, N.D. Rajesh, D.G. Wei, et.al., Synthesis of engineered particulates with tailored properties using dry particle coating, Powder Technology. Vol.117 (2001), p.46

DOI: 10.1016/s0032-5910(01)00314-x

Google Scholar

[13] X. Hao, G. Gai, Y. Yang, et.al., Development of the conductive polymer matrix composite with low concentration of the conductive filler, Materials Chemistry and Physics. Vol.109 (2008), p.15

DOI: 10.1016/j.matchemphys.2007.10.044

Google Scholar