New Polymeric Membrane Sensor Doped with N,N’-Bis(benzoin)-1,2-Phenylenediamine for Selective Determination of Aluminum

Abstract:

A new polymeric membrane sensor for Al³⁺ based on bis(benzoin)-1,2-phenylenediamine as a neutral carrier was investigated. The proposed sensor exhibits a near-Nernstian response for Al³⁺ over a wide linear range of 3.0×10^-7 to 1.0×10^-1 mol/L, with a detection limit of 1.0×10^-7 mol/L and a slope of 19.7±0.3 mV/decade. The sensor displays a good selectivity toward Al³⁺over other cations in pH range of 2.5 to 4.0. It has relatively fast response time (8 s) and can be used at least for 3 months without considerable divergence in potential. The response mechanism was discussed in view of the A.C. impedance technique. It was successfully used as an indicator electrode in the determination of aluminum in real samples.

• Periodical: Advanced Materials Research (Volumes 466-467)
• Pages: 336-341
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.466-467.336
• Online since: February 2012
• Authors: Xin Lu Liu, Bin Xie, Xun Hai Pan, Kang Quan Qiao, Ying Wang
• Keywords: Al³⁺ Sensor, Bis(benzoin)-1 2-Phenylenediamine, PVC Membrane

References

[1] M. Shamsipur, M. Yousefi, M. Hosseini, M.R. Ganjali, H. Sharghi and H. Naeimi: Anal. Chem. Vol. 73 (2001), p.2869.

[2] V.K. Gupta, A.K. Singh and B. Gupta: Anal. Chim. Acta Vol. 583 (2007), p.340.

[3] Y.H. Ma, R. Yuan, Y.Q. Chai and X.L. Liu: Anal. Bioanal. Chem. Vol. 395 (2009), p.855.

[4] L.V. Kochian: Ann. Rev. Plant Physiol. Mol. Biol. Vol. 46 (1995), p.237.

[5] T.M. Pietraszewska: Acta Biochim. Polon. Vol. 48 (2001), p.673.

[6] J.B. Hunn, L. Cleveland and E.E. Little: Environ. Poll. Vol. 43 (1987), p.63.

[7] N.E. W. Alstad, B.M. Kjelsberg, L.A. Vollestad and A.B.S. Poleo: Environ. Poll. Vol. 133 (2005), p.333.

[8] D. P. Perl and A.R. Brody: Sciecnce Vol. 208 (1980), p.297.

[9] J.L. Lin, M.T. Kou and M.L. Leu: Nephron Vol. 74 (1996), p.33.

[10] S.R. Paik, J.H. Lee, D.H. Kim and C.S. Chang: Arch. Biochem. Biophys. Vol. 344 (1997), p.325.

[11] M. Kawahara, K. Muramoto, K. Kobayashi, H. Mori and Y. Kuroda: Biochem. Biophys. Res. Commun. Vol. 189 (1992), p.1317.

[12] M. Kawahara, K. Muramoto, K. Kobayashi, H. Mori and Y. Kuroda: Biochem. Biophys. Res. Commun. Vol. 198 (1994). p.531.

[13] Y. Li, Y.Q. Chai, R. Yuan, W.B. Liang, L.N. Zhang and G.R. Ye: J. Anal. Chem. Vol. 63 (2008), p.1090.

[14] A. Abbaspour, A.R. Esmaeilbeig, A.A. Jarrahpour, B. Khajeh and R. Kia: Talanta Vol. 58 (2002), p.397.

[15] A. Yari, L. Darvishi and M. Shamsipur: Anal. Chim. Acta Vol. 555 (2006), p.329.

[16] M. Arvand and S.A. Asadollahzadeh: Vol. Talanta 75 (2008), p.1046.

[17] M.F. Mousavi, M. Arvand-Barmchi and M.A. Zanjanchi: Electroanalysis Vol. 13 (2001), p.1125.

DOI: 10.1002/1521-4109(200109)13:13<1125::aid-elan1125>3.0.co;2-7

[18] E.C. Horning: Organic Syntheses Collective Vol. 3 (Wiley, U.S.A. 1955, p.140).

[19] J.Z. Li, X.Y. Wei, F.G. Feng, H. Yang and S.Y. Qin: J. Sichuan Univ. Vol. 41 (2004), p.369.

[20] G.J. Moody, R. B. Oke and J.D. R Thomas: Analyst Vol. 95 (1970), p.910.

[21] S. Kamata, A. Bhale, Y. Fukunaga and A. Murata: Anal. Chem. Vol. 60 (1988), p.2464.

[22] M. Shamsipur, S. Rouhani, A. Mohajeri, M.R. Ganjali and P. Rashidi-Ranjbar: Anal. Chim. Acta Vol. 418 (2000), p.197.

DOI: 10.1016/s0003-2670(00)00954-5

[23] D.A. Chowdhury, T. Ogata, S. Kamata and K. Ohashi: Anal. Chem. Vol. 68 (1996), p.366.

[24] M.R. Ganjali, P. Norouzi, T. Alizadeh and M. Adib: Anal. Chim. Acta Vol. 576 (2006), p.275.

[25] Y. Umezawa, K. Umezawa and H. Sato: Pure Appl. Chem. Vol. 67 (1995), p.507.

[26] A. Mcnaughtan, K. Meney and B. Grieve: Chem. Eng. J. Vol. 77 (2000), p.27.