Study on the Photocatalytic Degradation of Diesel Pollutants over a Sol-Gel Prepared TiO2

Article Preview

Abstract:

Nanoscale titanium dioxide (TiO2) has been fabricated through a sound sol-gel method at room temperature with Tetra-n-butyl Titanate as the precursor, and the particles are characterized by XRD and TEM techniques. The results manifest that the as-prepared TiO2 is amorphous with the anatase structure and its size is around 33.2nm. Five factors, including dosage of TiO2, initial concentration of diesel, pH value, photocatalytic degradation reaction time and the presence of H2O2, are considered in the diesel degradation experiments. An orthogonal test is carried out to optimize the photocatalytic degradation of diesel pollutants based on the single-factor experiments. It reveals that when the dosage of TiO2 is 1.0g/L, the initial concentration of diesel is 0.5g/L, pH value is 6, the reaction time is 4h and the H2O2 dosage is 0.09%, the removal rate of diesel pollutants can up to 88%. Besides, the influence of each factor on removing diesel can be arranged in decreasing order: initial concentration of diesel> photocatalytic reaction time> pH value> TiO2 dosage> H2O2 dosage.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 476-478)

Pages:

1926-1929

Citation:

Online since:

February 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] V. V. Anikiev, V. A. Zorkin, and V. V. Anikiev: Chemical and Petroleum Engineering Vol. 40 (2004), p.353.

DOI: 10.1023/b:cape.0000039683.07691.ab

Google Scholar

[2] Seung Won Jung, Joon Sang Park, Oh Youn Kown, Jung-Hoon Kang, Won Joon Shim, and Young-Ok Kim: The Journal of Microbiology Vol. 48 (2010), p.594.

Google Scholar

[3] T. Ihaksi, T. Kokkonen, I. Helle, A.Jolma, T. Lecklin, S. Kuikka: Environmental Management Vol. 47 (2011), p.802.

DOI: 10.1007/s00267-011-9639-y

Google Scholar

[4] J. GRZECHULSKA, M. HAMERSKI and A. MORAWSKI: Wat. Res. Vol. 34(2000), p.1638.

Google Scholar

[5] D. P. Macwan, P.N. Dave, S. Chaturvedi: J Mater Sci. Vol. 46(2011), p.3669.

Google Scholar

[6] O. Carp, C.L. Huisman, A. Reller: Progress in Solid State Chemistry. Vol. 32-33(2004), p.177.

Google Scholar

[7] T. Klimova, M.L. Rojas, P. Castillo, R. Cuevas, J. Ramirez, Micropor. Mesopor. Mater. 20 (1998) p.293.

Google Scholar

[8] Y. Bessekhouad, D. Robert, and J.V. Weber: International Journal of Photoenergy. Vol. 5(2003), P. 153.

Google Scholar