Reduction of SSI by Hydrogen and its Microscopic Morphology

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Abstract:

Spherical sponge iron (SSI) with high activity and intension possesses potential characteristics to be utilized as wastewater treatment material, such as higher iron content, uniform particle size, higher compressive strength, etc. Observation on apparent morphology of exterior and microscopic morphology of SSI reduced by hydrogen under different temperature was carried on with SEM. When the reductive temperature was relatively lower than T4, the quantities of iron grain in exterior and interior of SSI increased with the increasing of temperature. When the temperature was elevated to T5, the particle size of iron grain was increased, and lots of macro-holes formed, especially in the interior section of SSI. When the temperature was T4, the SSI possesses more favorable ability to remove pollutant from wastewater. Moreover, the iron content in SSI was mostly reach to the summit under this temperature. In summarization, the reduction temperature should be controlled under T4 temperature if the sponge iron was utilized in wastewater treatment.

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672-676

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March 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Kumar, S. Chakraborty, Chemical denitrification of water by zero-valent magnesium powder. J Hazard. Mater., B135(2006) 112-121.

DOI: 10.1016/j.jhazmat.2005.11.031

Google Scholar

[2] G. C. C. Yang, H. L. Lee, Chemical reduction of nitrate by nanosized iron: kinetics and pathways. Water Res., 39(2005) 884-894.

DOI: 10.1016/j.watres.2004.11.030

Google Scholar

[3] Y. P. Feng, J. G. Li, N. Bi, X. L. Yan, Static experimental research on nitrate reduction removal from water by spherical sponge iron. Environ. Sci. and Technol., 6(2008) 14-18.

Google Scholar

[4] S. Choe, H. M. Liljestrand, J. Khim, Nitrate reduction by zero-valent iron under different pH regimes. Applied Geochem., 19(2004) 335-342.

DOI: 10.1016/j.apgeochem.2003.08.001

Google Scholar

[5] A. Yazdankhah, S. E. Moradi, S. Amirmahmoodi, M. Abbasian, S. E. Shoja, Enhanced sorption of cadmium ion on highly ordered nanoporous carbon by using different surfactant modification. Microporous and Mesoporous Mater., 1(2010) 35-53.

DOI: 10.1016/j.micromeso.2010.04.012

Google Scholar

[6] S. M. Ponder, J. G. Darab, T. E. Mallouk, Remediation of Cr(VI) and Pb(II) aqueous solutions using supported, nanoscale zero-valent iron. Environ. Sci. Technol., 12 (2000) 2564-2569.

DOI: 10.1021/es9911420

Google Scholar

[7] J. G. Li, J. Li, Y. G. Li, Cadmium removal from wastewater by sponge iron sphere prepared by charcoal direct reduction. J. Environ. Sci. suppl (2009) 60-64.

DOI: 10.1016/s1001-0742(09)60038-3

Google Scholar

[8] J. G. Li, L. H. Wei, Y. G. Li, N. Bi, F. F. Song, Cadmium removal from wastewater by sponge iron sphere prepared by hydrogen reduction. J. Environ. Sci. suppl. (2011) 114-118.

DOI: 10.1016/s1001-0742(11)61090-5

Google Scholar

[9] Y. R. Wang, J. G. Li, G. J. Zhao, L. X. Xu, Y. T. Li, In situ observations of microstructural and morphological changes of the reduction product of magnetite in H2/Ar gas mixtures. Acta Metall. Sinica. 6 (1998) 571-578.

Google Scholar