Photocatalytic Degradation of Active Brilliant Red on TiO2/SiO2 Composite Catalysts

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Abstract:

TiO2/SiO2 composite catalysts were prepared using two-step sol-gel method, with tetrabutyl titanate and tetraethyl orthosilicate as the main raw materials, and its photocatalytic properties for degradation of active brilliant red X-3B solution were researched throuth Ti:Si molar ratio, calcined temperature, initial concentration and photocatalyst dosage. The results indicate that the TiO2/SiO2 composite catalysts prepared with Ti:Si molar ratio of 6, calcination at 500°C have the best photocatalytic activity, and the photocatalytic activity of the composite materials is higher than that of pure TiO2 under the same conditions; moreover, it was found that degradation rate of active brilliant red X-3B solution increased with its lower initial concentration, and the optimum dosage of composite photocatalysts is 1.6g/L when the initial concentration of active brilliant red X-3B solution is 25mg/L.

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Advanced Materials Research (Volumes 488-489)

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221-225

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March 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] N.M. Mahmoodi, M. Arami N.Y. Limaee N.S. Tabrizi: Chem. Eng.J., Vol. 112(2005), p.191.

Google Scholar

[2] J Hoigne, H Bader: Water. Res. Vol. 10(1976), p.377.

Google Scholar

[3] M C Thurnauer, T Rajh, D M Tiede: Acta Chemical Scandinavica. Vol. 51(1997), p.610.

Google Scholar

[4] N Aiko, K Yoshizo, N Hiroyuki: Chem. Mater. Vol. 17(2005), p.6651.

Google Scholar

[5] G Wei, P T Carl: Langmuir. Vol. 21(2005), p.211.

Google Scholar

[6] Zhang H Z, Luo X H, Xu J: Phys. Chem. B. Vol. 108(2004), p.14866.

Google Scholar

[7] C L Wang, L Sun, K P Xie: Science in China Series B-Chemistry. Vol. 52(2009), p.2148.

Google Scholar

[8] L.Y. Shi, H.C. Gu, C.Z. Li, D.Y. Fang, Y. Zhang, B. Hua: Chinese J. of Cata. Vol. 20(1999), p.95.

Google Scholar

[9] S Sirakumar, C P Sibu, P Mukundan: Materials Letters. Vol. 58(2004), p.2664–2669.

Google Scholar

[10] M. Lǔ, P.G. Rao, J.Q. Wu: J. Sou. Chi. Uni. of Tech., Vol. 34(2006), p.95.

Google Scholar

[11] J.F. Ju, C.J. Li, M. Xu: Adv. In Fine Petrochem. Vol. 6(2005), p.4.

Google Scholar

[12] S. Erdemoglu, S.K. Aksu, F. Sayılkan, B. I˙zgi,M. Asilturk,H. Sayılkan, F. Frimmel, S Gucer: J. Hazard. Mater. Vol. 155(2008), p.469.

Google Scholar

[13] M. Huang, C. Xu, Z. Wu, Y. Huang, J. Lin, J. Wu: Dyes Pigments. Vol. 68(2006), p.53.

Google Scholar