Synthesis and Properties of Green Copolymer Retannage of Starch and Acrylamide with HRP/H2O2/ACAC

Sheng Hua Lv; Xiao Liang Yan; Qiang Cao

doi:10.4028/www.scientific.net/AMR.502.203

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Synthesis and Properties of Green Copolymer Retannage of Starch and Acrylamide with HRP/H₂O₂/ACAC
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 502Synthesis and Properties of Green Copolymer...

Synthesis and Properties of Green Copolymer Retannage of Starch and Acrylamide with HRP/H₂O₂/ACAC

Abstract:

A graft copolymer was synthesized by copolymerization of degraded starch and acrylamide using horseradish peroxidase (HRP)/H2O2/acetylacetone (ACAC) as initiator. The structure of the copolymer was confirmed by FTIR and NMR. The copolymer can be used as retannage in leather making substitute for chrome retannage and contribute to decreasing pollution. The applied results show that the retanned leather possesses merits of excellent soft feeling, good elasticity and uniform thickness.

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Periodical:

Advanced Materials Research (Volume 502)

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203-207

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.502.203

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Online since:

April 2012

Authors:

Sheng Hua Lv, Xiao Liang Yan, Qiang Cao

Keywords:

Graft Copolymerization, Horseradish Peroxidase (HRP), Modified Starch Retannage

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References

[1] M. Mohammad, S. Adeeb, Graft Copolymerization onto Starch-I. Synthesis and optimization of starch grafted with N-tert-butylacrylamide copolymer and its hydrogels, Journal of Polymer Research. 10 (2003) 119-125.

Google Scholar

[2] C. Youming, Q. Xiaosun, Graft copolymerization of acrylamide onto carboxymethyl starch, European Polymer Journal. 38 (2002) 1921-(1924).

DOI: 10.1016/s0014-3057(02)00077-0

Google Scholar

[3] S. Hui, W. Di, Z. Ruiquan, Synthesis and application of amphoteric starch graft polymer, Carbohydrate Polymers. 78 (2009) 253-257.

Google Scholar

[4] S. Hui, Synthesis and application of cationic starch graft polymer by using the complex initiation system, Carbohydrate Polymers. 82 (2010) 768-771.

DOI: 10.1016/j.carbpol.2010.05.049

Google Scholar

[5] M. Diana, T. Cristian, Biocatalytic microreactor incorporating HRP anchored on micro-/nano-lithographic patterns for ﬂow oxidation of phenols, Journal of Molecular Catalysis B: Enzymatic. 69 (2011) 133-139.

DOI: 10.1016/j.molcatb.2011.01.007

Google Scholar

[6] R. L. Shogren, J. L Willett, HRP-mediated synthesis of starch-polyacrylamide graft copolymers, Carbohydrate Polymers. 75 (2009) 189-191.

DOI: 10.1016/j.carbpol.2008.07.004

Google Scholar