Effects of Carrier on Supported Rare Earth Double Perovskite Oxide Catalysts for Catalytic Combustion of Methane

Abstract:

Supported rare earth double perovskite (La2MnNiO6) oxide catalysts were prepared by incipient wet impregnation method for methane catalytic combustion, and effects of the support (Al₂O₃, ZrO₂ and MgO) were investigated. The loaded catalysts were characterized by means of XRD, TPR, SEM techniques and their catalytic activities were tested by complete methane oxidation. Depending on the different oxide carrier (e.g. Al₂O₃, MgO and ZrO₂), catalysts have different catalytic properties, because the interaction of metal oxide-support will affect both redox property and dispersity of the active phase. The results on catalysts have shown that the dispersion on Al₂O₃ and MgO supports had an effect to enhance the catalytic performances of the catalysts that had been treated at 1100 oC. The activity of ZrO₂ supported catalyst significantly decreases when calcination temperature at is 1100 oC. The dispersity of the active phase and the nature of the oxide carrier played an important role in the catalytic performance.

• Periodical: Advanced Materials Research (Volumes 512-515)
• Pages: 1601-1606
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.512-515.1601
• Online since: May 2012
• Authors: Ran Ran Ding, Jia Nan Hu, Rui Sheng Hu, Ying Liu, Ling Jie Wang
• Keywords: Double Perovskite, Methane Catalytic Combustion, Support Effect

References

[1] Y. Q. Zhai, J. M. Xiong, C. Q. Li, X. Xu and G. H. Luo: submitted to Journal of Rare Earths (2010).

[2] S. Cimino, S. Colonna, S. De Rossi, M. Faticanti, L. Lisi, I. Pettiti and P. Porta: submitted to Journal of Catalysis (2002).

DOI: 10.1006/jcat.2001.3441

[3] Z. Jiang, J. J. Yu, J. Cheng, T. C. Xiao, M. O. Jones, Z. P. Hao and P. P. Edwards: submitted to Journal of Fuel Processing Technology (2010).

[4] G. Q. Guan, K. Kusakabe, M. Taneda, M. Uehara and H. Maeda: submitted to Journal of Chemical Engineering (2008).

[5] T. F. Tian, M. C. Zhan, W. D. Wang and C. S. Chen: submitted to Journal of Catalysis Communications (2009).

[6] S. V. Nguyen, V. Szabo, D. Trong On and S. Kaliaguine: submitted to Journal of Microporous and Mesoporous Materials (2002).

[7] E. E. Svensson, S. Nassos, M. Boutonnet and S. G. Järås: submitted to Journal of Catalysis Today (2006).

[8] B. de Collongue, E. Garbowski and M. Primet: submitted to Journal of Chemical Society, Faraday Transactions (1991).

[9] H.M. Zhang, Y. Teraoka and N. Yamazoe: submitted to Journal of Applied Catalysis (1988).

[10] R. Shaheen and J. Bashir: submitted to Journal of Solid State Sciences (2010).

[11] M. F. M. Zwinkels, O. Haussener, P. G. Menon and S. G. Jaras: submitted to Journal of Catalysis Today (1999).

[12] S. Ciminoa, L. Lisi, R. Pirone, G. Russo and M. Turco: submitted to Journal of Catalysis Today (2000).

[13] C. Batiot-Dupeyrat, G. Valderrama, A. Meneses, F. Martinez, J. Barrault and J. M. Tatibouët：submitted to Journal of Applied Catalysis A: General (2003).

DOI: 10.1016/s0926-860x(03)00155-8

[14] G. Pecchi, C. Campos, O. Peña and L. E. Cadus: submitted to Journal of Molecular Catalysis A: Chemical (2008).

[15] H. Q. Chen, H. Yu, F. Peng, G. X. Yang, H.J. Wang, J. Yang and Y. Tang: submitted to Journal of Chemical Engineering (2010).

[16] J. Y. Hu, W. Chu and L. Shi: submitted to Journal of Natural Gas Chemistry (2008).

[17] J. S. Yao, M. Meng, J. Y. Luo, Y. Q. Zha, Y. N. Xie, T .D. Hu and T. Liu: submitted to Journal of Molecular Catalysis (2006).

[18] L. M. Shi, W. Chu, F. F. Qu and S. Z. Luo: submitted to Journal of Catalysis Letters (2007).

[19] P. D. M. Mercera: submitted to Journal of Applied Catalysis (1991).

[20] W. M. Hua, A. Goeppert and J. Sommer: submitted to Journal of Applied Catalysis A: General (2001).