Kinetic Research of Boron Oxide Reducing Reaction at Low Temperature

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Abstract:

The reducing process of boron-containing slag at low temperature is an important stage of the direct alloying for smelting boron steel. At low temperature boron slag generates mainly solid - solid reaction in the sintering period. The experiments were done on the carbon tube furnace in laboratory, and the effect of slag reaction in different times at 1200°C was researched. The samples were analyzed by XRD after the reaction. The experimental results shown that the reduction rate increased by increasing reducing time. The chemical reducing reaction of boron oxide by ferrosilicon is second-order reaction at solid state.

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Advanced Materials Research (Volumes 512-515)

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2372-2375

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May 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] R. David. CRC handbook of chemistry and physics. Boca Raton: CRC Press, 2008: 10.

Google Scholar

[2] D. G. Zhao, P. M. Guo, P. Zhao. Activity model of Fe-Si-B ternary metallic melts. Journal of Iron and Steel Research, 2011, 18(6): 17~22.

DOI: 10.1016/s1006-706x(11)60071-x

Google Scholar

[3] D. G. Zhao, S. H. Wang, C. L. Wang, J. Gao. Thermodynamic research on smelting master alloy by direct reducing boron oxide. AMR Vols. 415-417 (2012) pp.848-852.

DOI: 10.4028/www.scientific.net/amr.415-417.848

Google Scholar

[4] D. G. Zhao, P. M. Guo, P. Zhao. Estimating model for standard entropy of intermetallics. Journal of University of Science and Technology Beijing, 2010, 32(1): 27.

Google Scholar

[5] C. C. Xu. Smelting technics of ferroalloy. Beijing: Metallurgical Industry Press, 2007: 293.

Google Scholar

[6] Y. X. Hua. Dynamic theory of metallurgy. Beijing: Metallurgical Industry Press, 2004: 222.

Google Scholar

[7] X. H. Huang. Priciple of I&S metallurgy. Beijing: Metallurgical Industry Press, 2002: 122.

Google Scholar

[8] S. B. Zhang, D. Z. Li. Phase diagram of principle, account and application in metallurgy. Beijing: Metallurgical Industry Press, 1986: 356.

Google Scholar

[9] J. Zhang. Calculating models of mass action concentrations for Fe-Si metallic melts. Journal of Iron and Steel Research, 1991, (2): 7.

Google Scholar