Effects of Alkaline Earth Metal on Combustion of Pulverized Coal

Article Preview

Abstract:

The influences of alkaline earth metal salts (CaO, MgO) on the combustion property of pulverized coal have been studied by thermogravimetric analysis (TGA). It was indicated that CaO and MgO could improve combustion characteristics of pulverized coal. It was demonstrated that the catalysis of CaO and MgO to the pulverized coal combustion was embodied in the enhancement of the emission of volatile matters (VM) from pulverized coal, which reduced the ignition temperature. MgO exhibited remarkably higher catalytic activity than that of CaO for the combustion of fixed carbon. MgO catalytic combustion mechanism for pulverized coal was different from that of CaO.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 516-517)

Pages:

271-275

Citation:

Online since:

May 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Kaczmarczyk J, Kordylewskl W, Zacharczuk W, et al. Development of porosity in calcium doped lignites during devolatilization and steam gasification[J]. Chem. Proc. Eng, 2008, 29(2): 425-436.

Google Scholar

[2] Xuzhong Gong, Zhancheng Guo, Zhi Wang. A thracite combustion ca talyzed by Ca-Fe-Ce series catalyst[J]. Journal of Fuel Chemistry and Technology (In Chinese). 2009, 37(4): 421-426.

Google Scholar

[3] Bao-Guo Ma, Xiang-Guo Li, Li Xu, et al. Investigation on catalyzed combustion of high ash coal by thermogravimetric analysis[J]. Thermochimica Acta, 2006, 445(1): 19-22.

DOI: 10.1016/j.tca.2006.03.021

Google Scholar

[4] Rubiera F, Arenillas A. Pevida C, et al. Coal structure and reactivity changes induced by chemical demineralization[J]. Fuel processing technology, 2002, 79(3): 273-279.

DOI: 10.1016/s0378-3820(02)00185-6

Google Scholar

[5] Boxiong Shen, Chunfei Wu, Lei Qin. MSW catalytic combustion by alkali and alkali-earth salts[J]. Energy, 2006, 31(4): 2900-2914.

DOI: 10.1016/j.energy.2005.10.033

Google Scholar

[6] C-Z.Li, C.Sathe, J.R. Fates and roles of alkali and alkaline earth metals during the pyrolysis of a Victorian brown coal[J]. Fuel, 2000, 79(5): 427-438.

DOI: 10.1016/s0016-2361(99)00178-7

Google Scholar

[7] Jie wang, Yihong Yao. Enhanced catalysis of K2CO3 for steam gasification of coal char by using Ca(OH)2 in char preparation[J]. Fuel, 2010, 89(3): 310-317.

DOI: 10.1016/j.fuel.2009.09.001

Google Scholar

[8] David Dollimore. A kinetic study of gaseous potassium capture by coal minerals in a high temperature fixed-bed reactor[J]. Fuel, 2008, 87(1): 3304-3312.

DOI: 10.1016/j.fuel.2008.05.003

Google Scholar

[9] Guheng Xu. Mechanism of Catalysed Ignition of coal[J]. Journal of Tongji university (natural science)(In Chinese), 1993, 21(3): 415-420.

Google Scholar