The Two-Photon Excited Fluorescence of Pyrazine Derivatives

Li Xiao Diao; Yue Zhi Cui; Xiang Jian Meng; Xing Wu Liu

doi:10.4028/www.scientific.net/AMR.535-537.1266

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 535-537The Two-Photon Excited Fluorescence of Pyrazine...

The Two-Photon Excited Fluorescence of Pyrazine Derivatives

Abstract:

A series of multi-branched pyrazine derivatives have been synthesized, of which, the two-branched one with para-branching pattern shows much enhanced two-photon absorption cross section (σ) than that with meta-branching pattern (1.8 times). The three-branched pyrazine derivative, in which the branches are at ortho- or para-position, show strong two-photon absorption properties (σ=753GM), while its s-triazine analogue TSTA, with all the branches in meta-position, exhibit too weak two-photon excited fluorescence to be detected. These results indicate great effects of branching pattern on two-photon absorption.

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Periodical:

Advanced Materials Research (Volumes 535-537)

Pages:

1266-1269

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.535-537.1266

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Online since:

June 2012

Authors:

Li Xiao Diao*, Yue Zhi Cui, Xiang Jian Meng, Xing Wu Liu

Keywords:

Multi-Branched, Pyrazine Derivatives, Two-Photon Excited Fluorescence

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