Investigation of Ionic Conduction and Morphological Properties of PMMA-Based Polymer Electrolytes Containing Lithium Iodide

Nurul Rozullyah Zulkepely; Siti Rohana Majid; Zurina Osman

doi:10.4028/www.scientific.net/AMR.545.264

Paper Titles

Reverse Micelle Liquid-Liquid Extraction of a Pharmaceutical Product
p.240

Structural, Physical and Mechanical Properties of Mg-Al Alloys Processed under CO₂ Atmosphere
p.247

Effect of Alloying Elements on the Microstructure and IMC Formation of SnAgCu Solder on Ni (P) Substrate
p.251

Ionic Transport in PMMA-NaCF₃SO₃ Gel Polymer Electrolyte
p.259

Investigation of Ionic Conduction and Morphological Properties of PMMA-Based Polymer Electrolytes Containing Lithium Iodide
p.264

Electrical and Magnetic Studies of (La_0.5-xPr_xBa_0.5)(Mn_0.5Ti_0.5)O₃ as Multiferroic Material
p.269

Impedance Spectroscopy Study of LiTaO₃Powder Synthesized via Sol-Gel Method
p.275

Structural and Electrical Properties of Lanthanide Substituted-Bismuth Titanate Prepared by Low-Temperature Combustion Synthesis
p.279

Structural and Electrical Characterization of Doped Zirconia Nanostructured Fibres
p.285

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 545Investigation of Ionic Conduction and...

Investigation of Ionic Conduction and Morphological Properties of PMMA-Based Polymer Electrolytes Containing Lithium Iodide

Abstract:

In this study, the two systems of polymethylmethacrylate (PMMA) based polymer electrolyte films have been prepared by the solution casting technique. Lithium iodide (LiI) and ethylene carbonate (EC) were used as inorganic salt and plasticizer, respectively. The highest room temperature conductivity for the plasticized system and unplasticized system is 4.42 x 10^-5 Scm^-1 and 4.37 x 10^-6 Scm^-1, respectively. The conductivity-temperature dependence studies have been performed on these films in the temperature range of 303 K to 373 K. It can be observed that the log σ versus 1000/T plots obey the Arrhenius rule and VTF rule for the plasticized film and unplasticized film, respectively [1-3]. The surface morphology of the plasticized and unplasticized films was observed by using scanning electron microscope (SEM).

You might also be interested in these eBooks

Advancement of Materials and Nanotechnology II

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 545)

Pages:

264-268

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.545.264

Citation:

Cite this paper

Online since:

July 2012

Authors:

Nurul Rozullyah Zulkepely, Siti Rohana Majid, Zurina Osman

Keywords:

Conductivity, LiI, Plasticizer, PMMA, Polymer Electrolyte, SEM

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] F.M. Gray, in Solid Polymer Electrolytes: Fundamentals and Technological Applications, VCH Publisher, New York, (1991).

Google Scholar

[2] W.A. Gazotti, M.A.S. Spinacé, E.M. Girotto, M. -A. De Paoli: Solid State Ionics Vol. 130 (2000), pp.281-291.

Google Scholar

[3] R. Baskaran, S. Selvasekarapandian, N. Kewata, J. Kawamura, T. Hattori: J. of Physics and Chemistry Vol. 68 (2007), pp.407-412.

Google Scholar

[4] T. Ijima, Y. Toyoguchi, N. Eda: Denki Kagaku Vol. 53 (1985), p.619.

Google Scholar

[5] T. Uma, T. Mahalingam, U. Stimming: Materials Chemistry and Physics Vol. 90 (2005), pp.245-249.

Google Scholar

[6] M. Deepa, S. A. Agnihotry, D. Gupta, R. Chandra: Electrochimica Acta Vol. 49 (2004), pp.373-383.

Google Scholar

[7] G. B. Appetecchi, F. Croce, B. Scrosati: Electrochimica Acta Vol. 40 (1995), pp.991-997.

DOI: 10.1016/0013-4686(94)00345-2

Google Scholar

[8] I. Nicotera, L. Coppola, C. Oliviero, M. Castriota, E. Cazzanelli: Solid State Ionics Vol. 177 (2006), pp.581-588.

DOI: 10.1016/j.ssi.2005.12.028

Google Scholar

[9] S. Ramesh, K. C. Wong: Ionics Vol. 15 (2009), pp.249-254.

Google Scholar

[10] X. Qian, N. Gu, Z. Cheng, X. Yang, E. Wang, S. Dong: Materials Chemistry and Physics Vol. 74 (2002), pp.98-103.

Google Scholar

[11] M. J. Reddy, T. Sreekanth, U. V. S. Rao: Solid State Ionics Vol. 126 (1999), pp.55-63.

Google Scholar

[12] D. F. Vieira, C. O. Avellaneda, A. Pawlicka: Electrochimica Acta Vol. 53 (2007), pp.1404-1408.

DOI: 10.1016/j.electacta.2007.04.034

Google Scholar

[13] R. Baskaran, S. Selvasekarapandian, G. Hirankumar, M. S. Bhuvaneswari: Journal of Power sources Vol. 134 (2004), pp.235-240.

DOI: 10.1016/j.jpowsour.2004.02.025

Google Scholar

[14] H. -J. Rhoo, H. -T. Kim, , J. -K. Park, T. -S. Hwang: Electrochimica Acta Vol. 42 (1997), pp.1571-1579.

Google Scholar