Reducibility of Oxide-Ion Conductors La2-XBaxMo2-YWyO9-δ

Article Preview

Abstract:

The reducibility of oxide-ion conductors La2-xBaxMo2-yWyO9-δ(x = 0, 0.06; y = 0, 0.1) were studied in the reducing atmosphere of 5%H2 + Ar by means of impedance spectroscopy measurement.. All substitutions can enhance the conductivity and improve the reducibility in the temperature range from 548 to 923 K. The double substitution of Ba and W has a better stabilizing effect than the single tungsten substitution.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

91-93

Citation:

Online since:

July 2012

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. Georges, F. Goutenoire, O. Bohnke, M.C. Steil, S.J. Skinner, H.D. Wiemhoefer, P. Lacorre, J. New Mater. Eletrochem. Syst. 7 (2004) 51.

DOI: 10.1002/chin.200449225

Google Scholar

[2] S. Georges, F. Goutenoire, Y. Laligant, P. Lacorre, J. Mater. Chem. 13 (2003) 2317.

Google Scholar

[3] S. Georges, O. Bohnke, F. Goutenoire, Y. Laligant, J. Fouletier, P. Lacorre, Solid State Ionics 177 (2006) 1715.

DOI: 10.1016/j.ssi.2006.02.036

Google Scholar

[4] F.J. Liang, X.P. Wang, Q.F. Fang, J.X. Wang, C. Li, D. Li, Z. Zhuang, Phy. Rev. B 74 (2006) 014112.

Google Scholar

[5] D.S. Tsai, M.J. Hsieh, J.C. Tseng, H.Y. Lee, J. Euro. Ceram. Soc. 25 (2005) 481.

Google Scholar

[6] X.P. Wang, Z.J. Cheng, Q.F. Fang, Solid State Ionics 176 (2005) 761.

Google Scholar

[7] X.P. Wang, D. Li, Q.F. Fang, Z.J. Cheng, G. Corbel, P. Lacorre, Appl. Phys. Lett. 89 2006) 021904.

Google Scholar

[8] D. Marrero-Lopez, J. Canales-Vazquez, J.C. Ruiz-Morales, J.T.S. Irvine, P. Nunez, Electrochim. Acta 50 (2005) 4385.

Google Scholar

[9] D. Marrero-Lopez, J. Canales-Vazquez, W.Z. Zhou, J.T.S. Irvine, P. Nunez, J. Solid State Chem. 179 (2006) 278.

Google Scholar

[10] Samuel Georges, Franc¸ois Goutenoire, Yvon Laligant and Philippe Lacorre, J. Mater. Chem. 13( 2003) 2317–2321.

Google Scholar

[11] F. Goutenoire, R. Retoux, E. Suard, P. Lacorre, J. Solid State Chem. 142 (1999) 228.

Google Scholar