Conversion of Glucose to Levulinic Acid Using SO42-/TiO2-Al2O3-SnO2 Solid Acid Catalysts

Jun Ping Zhuang; Xue Ping Li; Ying Liu

doi:10.4028/www.scientific.net/AMR.550-553.234

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 550-553Conversion of Glucose to Levulinic Acid Using...

Conversion of Glucose to Levulinic Acid Using SO₄^2-/TiO₂-Al₂O₃-SnO₂ Solid Acid Catalysts

Abstract:

Biomass represents an abundant and relatively low cost carbon resource that can be utilized to produce platform chemicals such as levulinic acid. This study focused on the effect of SO₄^2-/TiO2-Al₂O₃-SnO₂ solid acid catalyst on the catalytic performance in levulinic acid production from biomass-derived carbohydrates glucose. The SO₄^2-/TiO₂-Al₂O₃-SnO₂ solid acid catalyst showed a high catalytic activity for the selective conversion of glucose to levulinic acid. Experimental results showed that SO₄^2-/TiO₂-Al₂O₃-SnO₂ solid acid had markedly catalytic effects on the conversion of glucose to levulinic acid. With SO₄^2-/TiO₂-Al₂O₃-SnO₂ solid acid as the catalyst, an optimized ethyl levulinic acid was obtained at 180 °C for 2 h with glucose dosage of 2 wt% and 3 g SO₄^2-/TiO₂-Al₂O₃-SnO₂ solid acid catalys and the levulinic acid yield was 74.05%.

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Periodical:

Advanced Materials Research (Volumes 550-553)

Pages:

234-237

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.550-553.234

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Online since:

July 2012

Authors:

Jun Ping Zhuang, Xue Ping Li, Ying Liu

Keywords:

Catalyst, Glucose, Levulinic Acid, Solid Acid

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References

[1] Joshi H, Moser BR, Toler J, Smith WF, Walker TH. Biomass and Bioenergy, Vol 35(7) (2011) pp.3262-3266

DOI: 10.1016/j.biombioe.2011.04.020

Google Scholar

[2] Rackemann D W and Doherty W O. Biofuels, Bioprod. Bioref. Vol 5(2011):198–214

Google Scholar

[3] H. Oraby, B. Venkatesh, B. Dale, R. Ahmad, C. Ransom, J. Oehmke and M. Sticklen,. Transgenic Res, Vol 16 (2007) pp.739-749

DOI: 10.1007/s11248-006-9064-9

Google Scholar

[4] J P Zhuang, L Lin, C S Pang, Y Liu. Advanced Materials Research, Vol 236-238 (2011) pp.138-141

Google Scholar

[5] Saravanamurugan, S., Riisager, A. Catalysis Communications, Vol 17(5), (2012), pp.71-75

Google Scholar

[6] M J Niu, T M Gao, H D Yi. China Plastics Industry (In Chinese) Vol 32(2004), pp.11-12

Google Scholar

[7] L C Peng, J P Zhuang, L Lin. Journal of Natural Gas Chemistry Vol 21(2012), pp.138-147

Google Scholar

[8] Reddy B M, Sreekanth P M, Yamada Y, Xu X, Kobayashi T.Appl Catal A, Vol 228(2002), pp.269-278

Google Scholar