Decolorization Kinetics and Properties of Triphenodioxazine Reactive Dyes in Sodium Perborate-TAED Bleaching System

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Abstract:

The decolorization behaviors of a triphenodioxazine reactive dye (C.I. Reactive Blue 198) in the activated oxygen bleach system containing sodium perborate (PB) and tetra-acetylethylenediamine (TAED) were investigated. The decolorization kinetics of the dye was found to follow the first-order kinetic model and the rate constant of decolorization increased significantly with increasing temperature. The activation energy for decolorizing reaction was 50.41 kJ/mol. The highest rate constant appeared at pH 8. The triphenodioxazine reactive dye showed poor stability to activated oxygen washing.

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Advanced Materials Research (Volumes 550-553)

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2612-2615

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July 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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